SDBS复合强化超滤处理含镉废水的影响因素.pdfVIP

学兔兔 化 工 进 展 ·1468· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2009年第28卷第8期 纳米SiO2／SDBS复合强化超滤处理含镉废水的影响因素 庞治娟，周迟骏 (南京工业大学环境学院，江苏 南京 210009) 摘 要：以纳米 SiO2同阴离子表面活性剂十二烷基苯磺酸钠(SDBS)复合的胶束强化超滤处理含镉废水。考察 了粉体加入、pH值、粉体浓度对超滤的影响。结果表明，纳米SiO2加入后，膜通量提高了25％，CdE 截留率有 所提高，渗透液中SDBS的浓度在一定条件下有所降低。膜通量、SDBS及cd 的截留率随pH值的变化而变化， 三者随纳米SiO 加入量的增大而降低。另外，膜阻力主要为膜面吸附和膜孔堵塞阻力。 关键词：纳米SiO2；胶束强化超滤；含镉废水 中图分类号：X 703．1 文献标识Z-q：A 文章编号：1000—6613(2009)08—1468—05 Enhanced ultrafiltration for the wastewater treatment containing cadmium ions with nano Si02 and SDBS PANG Zhijuan，ZHOU ChUun (College ofEnvironment，Nanjing University ofTechnology，Nanjing 210009，Jiangsu，China) Abstract：The removal of Cd ions through ultrafiltration from aqueous solution using anionic surfactant SDBS added with nano SiO2 was studied．Effects of nano SiO2 addition and pH on the ultrafiltration process were investigated．The permeation flux was increased by 25％ through the addition of nano SiO7，the removal of Cd was alSO increased in some extent。while the permeated SDBS concenVafion became lowered．The permeation flux and the rejection of SDBS and Cd are affected by the pH of the solution，which would become lowered when increasing the nano SiO2 addition．In addition，the membrane fouling was mainly due to the the membrane surface adsorption resistance and the membrane pore blocking resistance． Key words：nano Si02：micell—enhanced ultraffltration；cadmium—containing wastewater 表面活性剂同超滤结合的胶束强化超滤技术已 研究表明，Triton．X的加入明显降低了SDS的临界 经成为从水中去除金属离子的一种颇有前景的方 胶束浓度 (