β分子筛负载钒催化剂丙烷氧化脱氢制丙烯.pdfVIP

学兔兔 石 油 化 工 · 1448· PETR0CHEMICAL TECHN0L0GY 2015年第44卷第12期 I]；分子筛负载钒催化剂丙烷氧化脱氢制丙烯 范爱鑫，聂素双，傅吉全，张聚华 (北京服装学院 材料科学与工程学院，北京 100029) [摘要]以B分子筛为载体，采用浸渍法制备不同V负载量的V／p系列催化剂，利用XRD，uv-vis，BET，H 一TPR，NH，-TPD 等手段对催化剂进行表征，考察Tv／f~催化剂丙烷氧化脱氢制丙烯的性能。表征结果显示，v／p催化剂的孔道均匀，孔分布 窄，有利于丙烷进入催化剂孔道与活性组分发生作用；负载较低V时催化剂中V物种主要以高度分散的孤立四配位V 形态存 在，随负载v含量的增加，二维链状聚集态v物种增加，负载V过多时易形成晶相V：0 ；负载的V覆盖了部分p分子筛自身的 酸性位，并在6分子筛表面产生弱酸性位，使丙烯的脱附变易，提高了丙烷转化率和丙烯选择性。实验结果表明，负载量8％ (W)的v／7催化剂在v(c H )：v(o2)：V(N )=2：1：4、气态空速8 400h- 、500℃时，丙烯选择性达63．2％。 [关键词]B分子筛；丙烷氧化脱氢；钒催化剂；丙烯 [文章编号]1000—8144(2015)12—1448—05 [中图分类号]TQ426．94 [文献标志码]A Oxydehydrogenation of Propane to Propene over B Zeolite Supported Vanadium Catalysts FanAixin，NieSushuang，FuJiquan，ZhangJuhua (School ofMaterials Science andEngineering，Beijing Institute ofFashionTechnology，Beijing 100029，China) [Abstract]A series of p zeolite supported vanadium catalysts(V／J3)with different V content were prepared through impregnation，and characterized by means of BET，XRD，UV-Vis，H2-TPR and NH3．TPD．Their performances in the oxydehydrogenation of propane to propene were studied．The results indicated that the v／13 catalysts with narrow pore size distribution and uniform pore size were beneficial to propane entering the channels in the catalysts and acting with active sites．The V species with lOW loading mainly existed in the form of four coordinated V”with high dispersity．With the V loading increasing，2 dimension linear aggregative V species formed，and when the V species overloading the V，Os crystal phase