不同结构活性炭对CO2、CH4、N2及O2的吸附分离性能.pdfVIP

学兔兔 化 工 进 展 ·206· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2009年第28卷第2期 不同结构活性炭对CO2、CH4、N2及o2的吸附分离性能 王玉新 ，苏 伟 ，周亚平 ( 天津大学理学院化学系，天津 300072； 天津大学化工学院高压吸附实验室，天津 300072) 摘 要：制备了比表面积为1943 m2／g的纯微孔活性炭AC一1和比表面积为1567 m2／g，中孔比例为47．18％的活性 炭AC一2。分别以AC一1及AC一2为吸附剂测定CO2、CH4、N2和02的298 K吸附等温线，考察了两种活性炭对 C02／N2、CO2／CH4及 CHdN2气体混合物的吸附分离性能。实验结果表明，孔结构是影响吸附剂吸附分离性能的 主要因素。富中孔活性炭AC一2较AC一1更适用于CO2／N2、CO2／CH4气体混和物的吸附分离，而微孔活性炭AC一1 对CHdN2混合体系的吸附分离性能优于AC一2。 关键词：活性炭；吸附；分离 中图分类号：TQ 424．1 文献标识码：A 文章编号：1000—6613(2009)02—0206—05 Adsorptive separation properties of activated carbons with different pore structures for CO2，CH4，N2 and O2 WANG Yuxin ，SU Wei ，ZHOU Yaping (1Department of Chemistry，College of Science，Tianjin University，Tianjin 300072，Cllina：2High Pressure Adsorption Laboratory，School of Chemical Engineering and Technology，Tianjin University，Tianjin 300072，China) Abstract-A micropore activated carbon(AC一1)with 1943m specific surface area and an activated carbon(AC一2)with 1567m ／g specific surface area and 47．18％mesopores were prepared．Adsorption iSOtherms of CO2，CH4，N2 and O2 on AC一1 and AC一2 were determined at 298K and the adsorption separation properties of the activated carbons for the mixtures of CO2／N2，CO2／CH4 and CH4／N2 were discussed．The results showed that the pore structure was the main factor affecting the adsorption separation properties of the activated carbons．AC．2 which with many mesopores was more suitable for the adsorptive separation of the mixtures of CO2／N2，CO2／CH4 than AC一1 with only micropores，while AC—1 was m