St-MA-AA酯化改性高分子分散剂的合成与应用.pdfVIP

学兔兔 化 工 进 展 ·2748· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2014年第33卷第10期 St．MA．AA酯化改性高分子分散剂的合成与应用 方淼，唐强，陈坤，徐保明 (湖北工业大学化学与化工学院，湖北 武汉 430068) 摘要：以苯乙烯(St)、马来酸酐(MA)、丙烯酸(AA)为单体，采用溶液聚合法合成三元共聚物，并用正丁醇 作酯化剂，对其进行部分酯化，制备出高分子分散剂 St—MA．AA部分酯化物。将此分散剂应用于酞菁蓝颜料表 面改性处理上，讨论了单体摩尔配比、分子量分布等因素对颜料平均粒径、Zeta电位、分散性(DE)和相对着 色力(Kr)的影响。结果表明，St、MA、AA单体最佳摩尔比为1：1：0．5时，自制分散剂st．MA．AA部分酯化 物与市售分散剂SMA1440相比，颜料的平均粒径降低了15％，Zeta电位上升了13％，离心稳定性升高了77％， 着色力增加了9％，分散效果明显更好。 关键词：苯乙烯．马来酸酐一丙烯酸共聚物；高分子分散剂；酞菁蓝；分散稳定性 中图分类号：TQ 322．44 文献标志码：A 文章编号：i000—6613(2014)i0—2748—06 DoI：10．3969~．issn．1000-6613．2014．10．038 Synthesis and application of partially esterified st—MA—AA as polymer dispersant FANG Miao，TANG Qiang，CHENKun，X-UBaoming (School ofChemistry and Chemical Engineering，Hubei University ofTechnology，Wuhan 430068，Hubei，China) Abstract：A polymeric dispersant was prepared from styrene，maleic and crylic acid as monomers by solution polymerization and partial esterification with -butano1．The surface modification treatment of copper phthalocyanine pigment by polymeric dispersant was studied．The influences of molar ratio， molecular size on properties ofparticle size ofthe pigment，Zeta potential，dispersity(DE)and relative tinctorial strength(KO were disscussed．The optimum molar ratio of St，MA，AA was 1：1：0．5．The self-made partially esterified St／MA／AA had better results on pigment dispersion than SMA1440，e．g．， the average particle size of the pigment was reduced by 1 5％，Zeta potential increased by 1 3％， centrifugal stability increased by 7