TA162824原油破乳剂的复配.pdfVIP

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TA162824原油破乳剂的复配

学兔兔 化 工 进 展 ·678· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 20 1 3年第32卷第3期 TA162824原油破乳剂的复配 石斌龙,张谋真,程 蝉,刘启瑞 (陕西省化学反应工程重点实验室,延安大学化学与化工学院,陕西延安716000) 摘 要:以有机胺为起始剂、环氧乙烷和环氧丙烷为单体、氢氧化钾为催化剂,合成嵌段聚醚型破乳剂单剂 TA162824,用TA162824分别与助剂TEAC和DMA按不同比例进行复配,用瓶试法分别对陕北油田的河庄坪 和子长原油进行脱水实验。结果表明,对河庄坪原油,在55℃,破乳剂总用量100 megL,脱水时问6 h时, TA162824与TEAC以2:3和3:2、与DMA以4:1的比例进行复配,脱水率最高,分别达到99.7%、97.8%; 对子长原油,在65℃,破乳剂总用量200 mg/L,脱水时间6 h时,TA162824与TEAC以2:3和1:4、与DMA 以4:1的比例进行复配,脱水率最高,分别达到97-3%和99-3%。其中TA162824与TEAC以2:3、与DMA 以4:1的复配物对这两种不同原油的脱水率等性能都好,适应性强。 关键词:原油;破乳剂;复配破乳剂;助剂 中图分类号:O647 文献标志码:A 文章编号:1000—6613(2013)03—0678—03 DOh 10.3969/j.issn.1000—6613.2013.03.033 Combinational demulsifiers of 162824 SHIBinlong,ZHANGMouzhen,CHENGChan,LIUQirui (ShaanxiKeyLaboratoryofChemicalReactionEngineering,CollegeofChemistryandChemical,Yan’anUniversity,Yan’all 716000,Shaanxi,China) Abstract:Using organic amine as primer,propylene oxide(PO)and epoxy ethane(EO)as monomer, po~sium hydroxide as catalyst,the TA162824 multi-block polyether demulsifier was synthesized and combined with TEAC and DMA at different proportions.Dehydration experiments of the combinational demulsifiers were conducted at 55。C in 6 h at demulsifier concentration of 100 mgm for Hezhuangping crudeoil,andat65℃ in6hatdemulsifierconcentrationof200mg/LforZichang crudeoilinNorthShaanxi oil fields by bottle test.1]he results showed that for Hezhuangping c

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