TiCl_4为原料掺碳二氧化钛的可见光催化活性.pdfVIP

学兔兔 化 工 进 展 ·562· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 201 1年第30卷第3期 TiCI4为原料掺碳二氧化钛的可见光催化活性 肖逸帆，柳 松，张连军，陈安琪 (华南理工大学化学与化工学院，广东 广州510640) 摘 要：为拓展二氧化钛对可见光的响应，采用水解法和其它步骤制备了碳掺杂二氧化钛粉末。用x射线衍射 和紫外一可见光漫反射吸收光谱以及X射线光电子能谱对制备的样品进行了表征，对可见光照射下的光催化活性 进行了测试，并考察了光催化的重复性。结果表明：碳掺杂致使二氧化钛在可见光区的光吸收增强，在降解甲 基橙的实验中表现出良好的可见光催化活性。 关键词：二氧化钛；光催化；碳掺杂；可见光 中图分类号：O 614．41 1 文献标志码：A 文章编号：1000—6613(2011)03—0562—05 Visible light photocatalytic activity of carbon doped titania photocatalyst prepared from TiCI4 XIAO Yifan，LIU Song，ZHANG Lianjun，CHENAnqi (School of Chemistry and Chemical Engineering，South China University of Technology Guangzhou 510640，Guangdong，China) Abstract：In order to expand the optical response of titania into the visible light region，carbon-doped titania powders were prepared by the hydrolysis method and other steps．The prepared samples were then characterized with XRD，XPS and UV—Vis diffuse reflectance spectroscopy．Moreover，the photocatalytic activities of the sam ples in the visible light region were tested，and the influences of different carbon resource on the photocatalytic activity were investigated．The doping of carbon led to an increase in optical absorption intensity in the visible light region，which result in high visible light photocatalytic activity with carbon doped titania in the decoloration of methyl orange． Key words：titania；photocatalysis；carbon doping；visible light TiO2被广泛地用作光催化剂，因为它有着良好 偶然发现，没有掺杂的样品也有光催化效果，从而 的光催化效果、化学稳定性、无毒无害、价格低廉