乙酸乙烯酯对魔芋葡甘聚糖的热塑改性.pdfVIP

维普资讯 学兔兔 化 工 进 展 CHEMICALINDUSTRYANDENGINEERINGPROGRESS 2008年第27卷第4期 乙酸乙烯酯对魔芋葡甘聚糖的热塑改性 张正光，罗学刚 (西南科技人学生命科学与工程学院，四川 绵阳 621000) 摘 要：首次采用乙酸乙烯酯对魔芋葡甘聚糖(KGM)进行改性，合成了不溶于水的可降解性KGM热塑新材料。 研究了不同工艺条件对KGM接枝共聚的影响，在引发剂浓度12 mmol／L、反应温度7O℃、反应时间3 h、单体 浓度0．52 mol／L条件下，KGM的接枝率和接枝效率较高。采用FHR、DSC、转矩流变仪等对改性材料的结构和 性能进行了分析表征。结果表明：KGM和乙酸乙烯酯之间发生了接枝共聚反应；改性材料的玻璃化转变温度仅 为O．12℃，在165℃处出现了熔融吸热峰，具有较好的热塑性；最大扭矩仅为8．5 N·m，塑化时间44 S，平衡 扭矩仅4 N·m，说明改性材料具有很好的热塑加工性能。 关键词：乙酸乙烯酯；魔芋葡甘聚糖；热塑材料；可降解 中图分类号：TQ 322．4 2 文献标识码：A 文章编号：1000—6613(2008)04—0590—05 Thermoplastic modification of konjac glucomannan with vinyl acetate ZHANG Zhengguang，LUO Xuegang (College ofLifeScience andEngineering，SouthwestUniversity ofScienceandTechnology，Mianyang621010， Sichuan，China) Abstract：A noveI material，thermoplastic konjac glucomannan(TKGM1 was synthesized from KGM， vinyl acetate(VAC、for the first time in this research．TtliS novel material is water resistant and degradable．The influence of different experimental conditions on the graft copolymerization was studied，and the optimal conditions were as follows：ammonium persulfate initiator concentration 12 mmol／L reaction time 3 h，reaction temperature 70℃，vinyl acetate concentration 0．52 mol／L．Th e structure and properties of TKGM were characterized wi山FTIR，DSC and torque rheometer．Th e results indicated that graft copolymerization reaction took place between KGM and VAc、The glass transition