不同取代度N,N-双十二烷基化壳聚糖的制备、表征及其单分子膜性能.pdfVIP

学兔兔 化 工 进 展 ·1272· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2010年第29卷第7期 不同取代度 Ⅳ_双十二烷基化壳聚糖的制备、 表征及其单分子膜性能 刘决照，李明春，辛梅华，明如镜 (华侨大学材料科学与工程学院，福建省高校功能材料重点实验室，福建 厦门361021) 摘 要：以壳聚糖和月桂醛为原料、十二烷基磺酸钠为相转移催化剂，制备 ⅣN-双十二烷基化壳聚糖 (N,N-DLCS)，并进一步分离成两种不同取代度的产物N,N-DLCS一1和 N-DLCS一2。用FTIR、EA和 H NMR 等方法进行表征，并研究其单分子膜性能。结果表明：N,N-DLCS一1的烷基取代度较高，N,N-DLCS一2较小。两 种样品均可在水面上形成单分子膜，其中N,N-DLCS一1的崩溃压 较高，极限分子占据面积A 较小，最大压缩 模量cs-1较大，单分子膜的凝聚性和稳定性更好。单分子膜的致密度和稳定性随着取代度的增加而增大。 关键词：壳聚糖；烷基化；取代度；单分子膜 中图分类号：O 636．1 文献标识码：A 文章编号：1000—6613(2010)07—1272—04 Preparation，characterization and monolayer properties of N,N-dialkyl chitosan with differente degree of substitution L／UJuezhao，LIMingchun，XINMeihua，MING Rujing (College of Material Science and Engineering，Huaqiao University，The Key Laboratory for Functional Materials of Fujian Higher Education，Xiamen 361021，Fujian，China) Abstract：With sodium dodecyl sulfonate as phase transfer catalyst，Ⅳ，N-dialkyl chitosan(Ⅳ．Ⅳ一DLCS一1 andⅣⅣ．DLCS一2)with different degree of substitution were prepared and characterized bv FTIR，EA and H NMR．Properties of monolayers of these two samples were alSO studied．Experimental results showed thatⅣ．Ⅳ一DLCS一1 has a higher degree of substitution，both samples could form a monolayer at the air-water interface．The sample N,N-DLCS—l showed higher collapse pressure 7rc，maximum compressibility modulus Cs_。and smaller extrapolated area Aex，the monolayer from which is more inseparable and stable due to the stronger interm olecular hydrophobic inte