反相微乳液法制备糊精纳米微球.pdfVIP

维普资讯 学兔兔 化 工 进 展 ·908· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2008年第27卷第6期 反相微乳液法制备糊精纳米微球 周 德，孙庆元 (大连工业大学生物与食品学院，辽宁 大连 l16034) 摘 要：以正己烷为油相，去离子水为水相，Span 60和Tween60为表面活性剂，正戊醇为助表面活性剂配制微乳液， 对影响微乳液特幽均各因素做了分析。并以糊精为原料，三偏磷酸钠为交联剂，制备糊精纳米微球。结果表明，在微乳 液体系中，表面活性剂的量与体系溶水能力在一定范围内正向相关，而助表面活性剂正戊醇对溶水能力则具有逆向作用。 红外光谱测试证实糊精与三偏磷酸钠发生交联，经扫描电镜观察，糊精微粒纳米形态均一，粒径在500~600nm之间。 关键词：反相微乳液；糊精；纳米微球；三偏磷酸钠 中图分类号：TQ 3l；TQ46 文献标识码：A 文章编号：l000—6613(2008)06—0908—05 Preparation of dextrin nanosphere with inverse microemulsion ZHOUDe，SUNQingyuan (College ofBiology Food Technology，Dalian Polytechnic University，Dalian 1 16034，Liaoning，China) Abstract：An inverse microemulsion was prepared with distilled water as water phase， 一hexane as organic phase，and Span 60 mixed with Tween 60 as emulsifying agent and -pentanol as co—emulsifying agent．The dextrin nanosphere was then prepared with the inverse microemulsion by using Na3P309 as cross—linking agent and dextrin as raw materia1．The results showed that the emulsif3，ing agent was in positive correlation to water solubility,whereas 一pentanol CO—emulsifying agent was in negative correlation to water solubility in the system of inverse microemulsion．The cross linking reaction taking place successfully was confirmed by infra—red spectrum analysis．A uniform dextrin nanosphere with a diameter of 500--600 nm was measured with scanning electronic microscope． Key words：inverse microemulsion；dextrin；dextrin