炭黑分散法制备双重孔分布的γ-Al_2O_3载体.pdfVIP

学兔兔 化 工 进 展 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2012年第3 1卷第3期 炭黑分散法制备双重孑L分布的Y．Al2o3载体 王雅菁 2，兰学芳L 2 张孔远L ，柴永明 ，赵瑞玉 ，刘晨光 (中国石油大学 (华东)， 重质油国家重点实验室， CNPC催化重点实验室，山东 青岛 266555) 摘 要：采用表面活性剂分散炭黑的方法对丫一A12O3进行扩孔，制备出孔径较大且孔分布集中的Y．A12O3载体。主 要考察了炭黑类型、炭黑用量及炭黑分散性，如分散剂类型、用量、超声时间等对1，．A12O3孔径分布的影响。结 果表明，传统的炭黑扩孔法存在用量大的缺点，采用分散剂结合超声处理的方法可在较低炭黑用量下(l0％) 取得良好的扩孔效果，制备出孔径分布集中于6am和10~20nn](或20~30am)的Y．A12O3载体。 关键词：氧化铝；炭黑；扩孔；双孔径分布 中图分类号：TE 624．9 5 文献标志码：A 文章编号：1000—6613(2012)03—0598—06 Preparation of dual pore size distributed 7-A1203 with pore·expanding agent of dispersed carbon black WANG Yajing ，LANXuefang ，2 ZHANG Kongyuan ～，CHAI Yongming ， ZHAO Ruiyu ～．LIU Chenguang ( State Key Laboratory ofHeavy Oil Processing， Key Laboratory ofCatalysis，CNPC China University ofPetroleum，Qingdao 266555，Shandong，China) Abstract：The T-AI203 carrier with large pore diameter and appropriate pore size distribution was prepared by using carbon black as an enlarge agent．The effects of carbon black types，content and dispersion in the 7-A1203 power，such as the chemical properties and content of surfactant dispersant， on the pore distribution of?-A1203 were studied．The results showed that dispersant agents，favoring the carbon black dispersion，could reduce the amount of carbon black and benefit the pore enlargement．By combining dispersant agents and sonication，the pore size distribution could be concentrated at 6nm and 10—2O nln(or 20—3O nm)with only 10％carbon black． Key words：alumina；carbon black；pore-expanding；dual pore size d