Observation of Different Catalytic Activity of Various 1-Olefins during Ethylene1-Olefin Copolymerization with Homogeneous Metallocene Catalysts 英文参考文献.docVIP

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Observation of Different Catalytic Activity of Various 1-Olefins during Ethylene1-Olefin Copolymerization with Homogeneous Metallocene Catalysts 英文参考文献.doc

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Observation of Different Catalytic Activity of Various 1-Olefins during Ethylene1-Olefin Copolymerization with Homogeneous Metallocene Catalysts 英文参考文献

Molecules 2011, 16, 373-383; doi:10.3390/moleculeOPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Observation of Different Catalytic Activity of Various 1-Olefins during Ethylene/1-Olefin Copolymerization with Homogeneous Metallocene Catalysts Mingkwan Wannaborworn, Piyasan Praserthdam and Bunjerd Jongsomjit * Center of Excellence on Catalysis and Catalytic Reaction Engineering, Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok 10330, Thailand * Author to whom correspondence should be addressed; E-Mail: bunjerd.j@chula.ac.th; Tel.: +66 2 2186869; Fax: +66 2 2186877. Received: 18 November 2010; in revised form: 28 December 2010 / Accepted: 5 January 2011 / Published: 7 January 2011 Abstract: This research aimed to investigate the copolymerization of ethylene and various 1-olefins. The comonomer lengths were varied from 1-hexene (1-C6) up to 1-octadecene (1- C18) in order to study the effect of comonomer chain length on the activity and properties of the polymer in the metallocene/MAO catalyst system. The results indicated that two distinct cases can be described for the effect of 1-olefin chain length on the activity. Considering the short chain length comonomers, such as 1-hexene, 1-octene and 1-decene, it is obvious that the polymerization activity decreased when the length of comonomer was higher, which is probably due to increased steric hindrance at the catalytic center hindering the insertion of ethylene monomer to the active sites, hence, the polymerization rate decreased. On the contrary, for the longer chain 1-olefins, namely 1-dodecene, 1- tetradecene and 1-octadecene, an increase in the comonomer chain length resulted in better activity due to the opening of the gap aperture between Cp(centroid)-M-Cp-(centroid), which forced the coordination site to open more. This effect facilitated the polymerization of the e