Shape-Memory Properties of Segmented Polymers Containing Aramid Hard Segments and Polycaprolactone Soft Segments 英文参考文献.docVIP

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Shape-Memory Properties of Segmented Polymers Containing Aramid Hard Segments and Polycaprolactone Soft Segments 英文参考文献.doc

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Shape-Memory Properties of Segmented Polymers Containing Aramid Hard Segments and Polycaprolactone Soft Segments 英文参考文献

Polymers 2010, 2, 71-85; doi:10.3390/polym2020071 OPEN ACCESS polymers ISSN 2073-4360 /journal/polymers Article Shape-Memory Properties of Segmented Polymers Containing Aramid Hard Segments and Polycaprolactone Soft Segments Christian Schuh, Kerstin Schuh, Maria C. Lechmann, Louis Garnier and Arno Kraft * Chemistry, School of Engineering Physical Sciences, Heriot-Watt University, Edinburgh EH14 4AS, UK; E-Mails: schuh@imtek.de (C.S.); kschuh@imtek.de (K.S.); lechmann@mpip-mainz.mpg.de (M.C.L.); louis_garnier@hotmail.fr (L.G.) * Author to whom correspondence should be addressed; E-Mail: a.kraft@hw.ac.uk; Tel.: +44-131-4518040; Fax: +44-131-4513180. Received: 27 April 2010; in revised form: 28 May 2010 / Accepted: 28 May 2010 / Published: 8 June 2010 Abstract: A series of segmented multiblock copolymers containing aramid hard segments and extended polycaprolactone soft segments (with an Mn of 4,200 or 8,200 g mol–1) was prepared and tested for their shape-memory properties. Chain extenders were essential to raise the hard segment concentration so that an extended rubbery plateau could be observed. Dynamic mechanical thermal analysis provided a useful guide in identifying (i) the presence of a rubbery plateau, (ii) the flow temperature, and (iii) the temperature when samples started to deform irreversibly. Keywords: shape-memory polymer; aramid; polycaprolactone 1. Introduction When an elastic material is deformed, elastic energy is stored within the material but is immediately recovered once the applied stress is released [1,2]. In contrast, deformation of a shape-memory material leads to a stable temporary shape. As in the case of an elastomer, elastic energy is stored within the material; however, unlike an elastomer, its release requires the application of an external trigger which is usually heat but can also be a magnetic field or light [3,4]. Shape-memory alloys such as nickel– titanium alloy (Nitin