Spectroscopic Interpretation of PAH-Spectra in Minerals and Its Possible Application to Soil Monitoring 英文参考文献.docVIP

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Spectroscopic Interpretation of PAH-Spectra in Minerals and Its Possible Application to Soil Monitoring 英文参考文献.doc

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Spectroscopic Interpretation of PAH-Spectra in Minerals and Its Possible Application to Soil Monitoring 英文参考文献

Sensors 2010, 10, 3868-3881; doi:10.3390/s100403868 OPEN ACCESS sensors ISSN 1424-8220 /journal/sensors Article Spectroscopic Interpretation of PAH-Spectra in Minerals and Its Possible Application to Soil Monitoring Eun-Joung Ko 1, Kyoung-Woong Kim 1,*, Kihong Park 1, Ju-Yong Kim 1, Jiwon Kim 1, Se-Yeong Hamm 2, Jung-Hwan Lee 2 and Uwe Wachsmuth 3 1 Department of Environmental Science and Engineering, Gwangju Institute of Science and Technology, 1 Oryong-dong, Buk-gu, Gwangju 500-712, Korea; E-Mails: ejko@kird.re.kr (E.-J.K.); kpark@gist.ac.kr (K.P.); juyongk@gist.ac.kr (J.-Y.K.); jiwonkim1219@ (J.K.) 2 Division of Earth Environmental System, College of Natural Science, Pusan National University, Busan 600-735, Korea; E-Mails: hsy@pusan.ac.kr (S.-Y.H.); oathway@pusan.ac.kr (J.-H.L.) 3 Laser Laboratorium Goettingen, Hans-Adolf-Krebs-Weg 1, 37077 Goettingen, Germany; E-Mail: uwachsmuth@llg-gmbh.de * Author to whom correspondence should be addressed; E-Mail: kwkim@gist.ac.kr; Tel.: +82-62-715-2432; Fax: +82-62-715-0877. Received: 3 February 2010; in revised form: 6 April 2010 / Accepted: 7 April 2010 / Published: 15 April 2010 Abstract: In order to properly assess the feasibility of using Laser-Induced Fluorescence (LIF) spectroscopy for soil monitoring, the variation of fluorescence intensity due to the heterogeneity and complexity of soil media was investigated. Different soil minerals showed fluorescence spectral structures distinguishable from the contaminants, implying dissimilar interactions or the binding of contaminants on mineral surfaces. More interestingly, solvent and water addition showed different responses in the fluorescence spectral structure showing their effect on the interactions between contaminants and minerals. These results support the claim that the spectral structure contains information on contaminant-mineral interactions; therefore contaminants can be used as a fluorescence probe for these i