从氧化锌矿制备活性氧化锌工艺条件研究1.docVIP

从电石渣中回收氧化钙的工艺研究与生产实践 田伟军1赖乃斌2 (湖南化工职业技术学院 湖南株洲 412004 湖南株洲 412004 )摘　要：研究了以电石渣为原料回收氧化钙的工艺，主要过程包括：原料预处理、杂质分离、电石渣煅烧分解等。重点考察了除杂及煅烧工艺条件，结果表明：得到的氧化钙产品含量可达到?85%以上应用该工艺建成了一套10000t/a生产装置结构简单生产过程控制方便可靠、 关键词　电石渣；回收；氧化钙；生产 rocess research and production practice of recovering calcium oxide from carbide slag Tian Wei-jun1,Lai Nai-bin2 (1 Hunan Chemical Vocational and Technical College HuNan Zhuzhou 412004； 2 China Salt Industry Group, Hunan Zhuzhou Chemical Industry Group HuNan Zhuzhou 412004) Abstract :This paper studied the carbide slag as raw material recovery process calcium oxide, the main process includes: pre-processing of raw materials, impurity separation, decomposition of carbide slag calcined. It inspected the impurity and the calcination process conditions, results showed that: the hydrocyclone impurity removal process, control the flow rate of 0.10m / s detachable carbide slag in the mechanical impurities, the temperature at 900 ℃ calcined 5h, calcium oxide obtained product content can reach 85% or more, the application of the process into a set of 10000t / a of the production plant. Device operational status showed: calcium oxide materials and devices out of micro-negative pressure operation to solve the problem of dust pollution in order to take full advantage of coal-water slurry as fuel and exhaust gas waste heat to reduce energy consumption. Using rotary kiln calcining, device structure is simple, convenient and reliable process control of production, processing capacity, high degree of automation. Key words: carbide slag; recovery; calcium oxide; production 前言 氧化钙是无机碱性腐蚀物品，主要用作化工原料、建筑材料、、干燥剂以及土壤改良剂等。电石渣是电石水解获取乙炔气后的以氢氧化钙为主要成分的废渣来源于聚氯乙烯、乙炔、聚乙烯醇等化工产品的生产。我国聚氯乙烯的生产方法主要有乙烯法和电石法两种，由于石油价格居高不下，作为煤化工重要分支的电石-乙炔路线化工产品（如溶解乙炔、聚氯乙烯等）竞争优势凸显，进入高速发展阶段。随着聚氯乙烯行业快速发展，电石将迎来投产高峰，电石渣的量将会大幅增加。回收利用电石渣的途径较多，主要有以下几个方面：用电石渣代替钙质材料生产建筑材料如生产水泥、作为普通建筑材料、作防水涂料的主要填料、生产建筑砌砖等；用于生产化工产品代替石灰生产过氧化钙、与氯气作用生产漂白粉(液、精)、制成石灰作为电石的生产原料、生产CaCO3系列产品等用于环境治理如处理酸性废水、废气，作锅炉烟气的脱硫吸收剂、作劣质煤的固硫剂等。但回收加工生产氧化钙的研