物化实验 电池电动势的测定及其应用.pdfVIP

USTC 鐗╃悊鍖栧瀹為獙鎶ュ憡 瀹為獙鍏 鐢垫睜鐢靛姩鍔跨殑娴嬪畾鍙婂叾搴旂敤 EXPERIMENT 6 锛 The Measurement Application of Electromotive Force 寮犱粯鐟 P 鍖栧涓庢潗鏂欑瀛﹀闄 鏉愭枡绉戝涓庡伐绋嬬郴 Department of Materials Science Engineering锛孲chool of Chemistry and Materials Science USTC 鐗╃悊鍖栧 瀹為獙鎶ュ憡 2013 骞寸浜屽鏈熷疄楠屾姤鍛 USTC 鏉愭枡绉戝涓庡伐绋嬬郴 寮犱粯鐟 P 椤 0 USTC 鐗╃悊鍖栧瀹為獙鎶ュ憡 鐢垫睜鐢靛姩鍔跨殑娴嬪畾鍙婂叾搴旂敤 路鎽樿锛 鏈疄楠屼互閾?姘寲閾剁數鏋佷负鍙傛瘮鐢垫瀬锛屾祴閲忎簡閾?纭吀閾滅數鏋佺殑鏍 鍑嗙數鏋佺數鍔匡紝浠ュ強閾?纭濋吀閾剁數鏋佺殑鏍囧噯鐢垫瀬鐢靛娍銆傚叾涓繍鐢ㄧ殑 閲嶈鏂规硶鏄娑堟硶锛屾祴寰椾簡杩戜技鍙€嗙姸鎬佷笅鐨勭數姹犵數鍔ㄥ娍銆傛牴鎹 绗簩涓數姹犲弽搴旇绠楀緱鍒颁簡姘寲閾剁殑婧跺害绉 Ksp锛岀敱鍏剁數姹犵殑鐢 鍔ㄥ娍闅忔俯搴﹀彉鍖栨洸绾匡紝鏍规嵁 Nernst 鏂圭▼鍜 Gibbs -Helmholtz 鏂 绋嬭绠楀緱鍒拌鍙嶅簲鐨勬爣鍑嗘懇灏斿弽搴旂創鍙樸€佺喌鍙樺拰鍚夊竷鏂嚜鐢辫兘鍙 鍖栥€ 路鍏抽敭璇嶏細 鍙€嗙數姹 鐢靛姩鍔 鐢垫瀬鐢靛娍 婧跺害绉 鐑姏瀛﹀嚱鏁 路Abstract锛 In this experiment, we use silver-silver chloride electrode as reference electrode and measure the standard electrode potential of both the electrode of Cu-copper sulfate and the electrode of the silver-silver nitrate. During the experiment, we use the cancellation method to measure the potential of electrode in a closely reversible situation. According to the second reaction, we got solubility product Ksp of silver chloride. Besides the curve of its electromotive force of the battery with the temperature, according to the Nernst equation and Gibbs - Helmholtz equation we could get the standard molar reaction enthalpy change, entropy change and Gibbs free energy change. USTC 鐗╃悊鍖栧瀹為獙鎶ュ憡 鐢垫睜鐢靛姩鍔跨殑娴嬪畾鍙婂叾搴旂敤 路Keyword: Reversible battery, EMF, Electrode potential, the Solubility Product, Thermodynamic Functions