16单元丁苯橡胶..pptx

UNIT 16 Styrene-Butadiene Copolymer;简介;发展史;分类;应用;Words and Expressions;Phenyl [′fen?l] n.苯基 Naphthylamine [n?f′θ?le?m?n] n.萘胺 Latex [′le?teks] n.胶乳，乳液 Coagulate [k??′?gjule?t] v. 凝聚 Brine [bra?n] n.盐水 Sulfuric acid n. 硫酸 Crumb [kr?m] n. 碎屑，团粒 Bale [be?l] v. 打包 Abnormal [?b′n?:ml] a.反常的 Extender [?ks′tend?] n. 添加物[剂]，增量剂 sacrifice [?s?kr?fa?s] v.牺牲，损失 ; lighter-colored 浅色的 dithiocarbamate [da?′θa?o?′kɑ:b?me?t] n. 二硫代氨基甲酸盐 Chain-transfer agent 链转移剂 Objectionable a. 反对的，使人不愉快的 Dimethydithiocarbamate n. 二甲基二硫代氨基甲酸盐 Sodium [′so?di?m] n. 钠 Tert-dodecyl mercaptan n. 特十二烷基硫醇 Diisopropylbenzene n. 二异丙苯 Ferrous sulfate heptahydrate n. 硫酸亚铁七水合物 ; Pyrophosphate [?pa?r?f?s?fe?t] n.焦磷酸盐 Aluminum sulfate n.硫酸铝 Ethylenediaminetetraacetate n.乙二胺四乙酸盐 Dece- [构]十 Tetra- [构]四 Formaldehyde [f?:r?m?ld?ha?d ] n.甲醛 Sulfoxylate [s?lf?ks?le?t] n.次硫酸盐 Rosin acid n.松香酸 Dissociation [d??sosi?e??n] n.分裂、分离、离解 Persulfate [p?s?lfe?t] n.过硫酸盐 Menthane [menθe?n] n.薄荷烷 Redox [?ri?dɑks] n.氧化还原作用 ;The synthetic rubber industry, based on the free-radical emulsion process, was created almostovernight during World War II. Styrene-butadiene (GR-S) rubber crated at that time gives such good tire treads that natural rubber has never regained this market.;The GR-S standard recipe is 丁苯橡胶的标准制法是;混合物在搅拌下50℃加热，每小时转化5%～6%，在转化率达70%～75%时通过加入“终止剂” 聚合反应终止，例如对苯二酚（大约0.1的重量百分含量），抑制自由基并避免过量支化和微凝胶形成。;Unreacted butadiene is removed by flash distillation, and syrene by steam-stripping in a column. After addition of an antioxidant, such as N-phenyl-β-naphthylamine (PBNA) (1.25 parts), the late