Cu-OMS-2催化甲醇氧化羰基化合成碳酸二甲酯-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2011年第40卷第4期 PETRoCHEMICAL TECHN0L0GY ·369· Cu—OMS一2催化甲醇氧化羰基化 合成碳酸二甲酯 周 炬，陈启明，杨小俊 (武汉工程大学 绿色化工过程教育部重点实验室，湖北 武汉 430073) [摘要]采用固态离子交换法制备了Cu—OMS一2催化剂，并通过XRD，SEM，XPS对催化剂进行了表征，将其用于甲醇氧化羰 基化合成碳酸二甲酯(DMC)反应，分析了催化剂的物相和形貌对其催化活性的影响。实验结果表明，Cu—OMS一2催化剂对合 成DMC有较好的催化性能，其原因是：(1)CuC1以薄片形式均匀堆积排列分布在载体表面，有利于反应物的吸附；(2)催化剂中 Cu 和Cu 以合适的比例存在时有利于 DMC的合成。采用CuC1负载量(质量分数)为25％、500℃下焙烧5 h制备的Cu— OMS一2催化剂，在优化的反应条件下，DMC的收率达84．6％。 [关键词]碳酸二甲酯；甲醇；氧化羰基化；锰氧八面体分子筛；铜催化剂 [文章编号]1000—8144(201I)04—0369—07 [中图分类号：TQ 225．52 [文献标识码j A Oxidative Carbonylation of Methanol to Dimethyl Carbonate over Cu·OMS-2 Catalyst Zhou Xuan，Chen Qiming，Yang Xiaojun (Key Laboratory for Green Chemical Process of Ministry of Education，Wuhan Institute of Technology，Wuhan Hubei 430073，China) [Abstract] Cu—OMS一2 catalysts were prepared by solid—state ion—exchange method and used in oxidative carbonylation of methanol to dimethy1 carbonate．The catalysts were characterized by means Of XRD．SEM and XPS．The effects of the crystalline phase and structure on the catalyst activity in the oxidative carbonylation were investigated．The results showed that the good catalytic performance of Cu一0MS一2 catalyst could be attributed to the appropriate proportion between Cu“ and Cu in the catalyst．CUC1 existed in thin slice fornl and dispersed well on the catalyst surface．which was beneficial to adsorption of the reactants．Among the used catalysts．the Cu—OMS一2 catalyst with 25％(W)CuC1 loading and calcinated at 500 oC fo