生物可降解脂肪芳香共聚酯增韧改性聚乳酸-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2014年第43卷第5期 PETR0CHEMICAL TECHNOLOGY ·561· 生物可降解脂肪芳香共聚酯增韧改性聚乳酸 祝桂香，张 伟，韩 翎，许 宁，计文希 (中国石化 北京化工研究院，北京 100013) [摘要]以自主研发合成的生物可降解脂肪芳香共聚酯——聚(丁二酸丁二醇一对苯二甲酸丁二醇)酯(PBST)(以1，4一丁二 酸、1，4一丁二醇和对苯二甲酸为单体原料)为增韧改性剂，对脆性的聚乳酸(PLA)进行共混增韧改性，研究了PBST~1人量对 PLA／PBST共混物力学性能的影响，并结合DSC曲线研究了PLA／PBST共混物的结晶度和结晶能力的变化，从微观形态阐述了 PBST~PLA的宏观增韧改性机理。实验结果表明，当m(PLA)：m(PBTS)=60：40～40：60时，PLA／PBST共混物具有较高 的力学强度(拉伸屈服应力最大可达31．6 MPa)、较大的断裂伸长率(与纯PLA相比，增大了近50倍)和较高的缺口冲击强度 (最大可达8．16 kJ／m )，是一类力学综合性能优异的生物可降解塑料。 [关键词]生物可降解塑料；聚乳酸；脂肪芳香共聚酯；增韧 [文章编号]1000—8144(2014)05—0561—05 [中图分类号]TQ 325 l文献标志码]A Toughening Modification of Polylactic Acid with BiOdegradable Aliphatic—Aromatic Copolyester Zhu Guixiang，Zhang Wei，Han Ling，Xu N g，Ji Wenxi (SINOPEC Beijing Research Institute ofChemical Industry，Beijing 100013，China) [Abstract]Polylactic acid(PLA)was modified by blending with a self-made biodegradable aliphatic— aromatic copolyester，poly(butylene succinic—CO—butylene terephthalate)(PBST)，for toughening．The effects of PBST dosage on the mechanical properties of the PLA／PBST blends were investigated．The influences of PBST on the crystallinity and crystallization ability of the blends were studied by means of their DSC curves．The mechanism of the toughening modification was explored according to the microcosmic morphology of the blends．The experimental results showed that the blend with PBST of 40％-60％(w)possessed high mechanical strength(tensile yield stress 3 1．6 MPa)，large elongation at break(50 times larger than that ofpure PLA)，and high charpy notched impact strength(8．16 kJ／