甲醇-苯-1-辛基-3-甲基咪唑四氟硼酸盐物系汽液平衡的测定-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2011年第40卷第5期 PETR0CHEMICAL TECHN0L0GY ·541· 甲醇一苯一1 辛基一3一甲基咪唑四氟硼酸盐物系 汽液平衡的测定 李群生，Magtuf Zuhir，朱 炜，付永泉，李 仑 (北京化工大学 化学工程学院，北京 100029) 『摘要1在101．32 kPa下，用改进的Othmer釜测定了甲醇一苯一1一辛基一3一甲基咪唑四氟硼酸盐([OMIM]BF4)物系的等压 汽液平衡数据；采用UNIFAC方程对实验数据进行了关联。实验结果表明，加入离子液体[OMIM]BF4使汽液平衡线偏离甲醇一 苯二组分物系的汽液平衡线，[OMIM]BF4含量越大，偏离程度越大。[OMIM]BF4具有明显的盐析效应，能增大甲醇与苯的相对 挥发度，随[OMIM]BF4含量的增加，甲醇与苯的相对挥发度增加，当 ([OMIM]BF4)=30％时，甲醇一苯物系的共沸点消失。 『OMIM]BFd可作为甲醇一苯物系萃取精馏的溶剂。 [关键词]甲醇；苯；1一辛基一3一甲基咪唑四氟硼酸盐；汽液平衡；离子液体；UNIFAC方程 [文章编号]1000—8144(2011)05—0541—04 [中图分类号]TQ 013．1 [文献标识码]A Isobaric Vapor——Liquid Equilibrium for Methanol-Benzene- 1一Octyl-3一Methylimidazolium Ternary System Li Qunsheng，MagtufZuhir，Zhu Wei，Fu Yongquan，Li Lun (College of Chemical Engineering，Beijing University of Chemical Technology，Beijing 100029，China) [Abstract] Isobaric vapor—liquid equilibrium about methanol—benzene一1一octyl一3一methylimidazolium ([OMIM]BF4)system was measured at 101．32 kPa using a modified Othmer stil1．The experiment results showed that the ionic liquid[OMIM]BF4 exhibited notable salting—out effect which could enhance the relative volatility．When the mole fraction of[OMIM]BF4 amounted to 30％，the azeotropic point disappeared and the relative volatility of the system increased with the increase of the mole fraction of[OMIM]BF4．UNIFAC equation was used to correlate and predict the experimental data．As a result，it is concluded that[OMIM]BF4 can be taken on as a solvent of the extractive distillation for methanol—benzene system．The suitable mole fraction of