含银PA6纳米纤维的直径分布及其抗静电性能.doc

第粥卷筹5期 绣缓学援 V《．30 No。5 2009年5月 May 2009 Journal of Textile Research 文章编号：0253．9721{2009)05-0011-05 含银PA6纳米纤维的直径分布及其抗静电性能 王鸿博，王 曦，何艳丽，于 航，高卫东，李 静，蒋玲玲 (生态纺织教学部重点实骏宣(江南火学)，江苏无锡214122) 捕娄为研兜含银聚酰胺6(PA6)纳米纤维的直径分布和性虢，采用静电纺丝技术，制备不同含锿量的PA6纳米 纤维毡。利用捆描电镜及棚关软件，分析纳米纤维直径分布及形态，在银溶胶质量分数为0．1％一0．4％、纺丝液质 璧分数为10％一16％懿实骏莲蓬凑，纳米纾缝乎均赢径秀钧一90 rim；绫拳纤维妻弪隧镊溶菠凌爨分数鹣增熊瓤藏 小，随纺丝液鹰量分数增多丽增大。透射电镜(TEM)分析表明：纳米银在纤维中分帝均匀，状态懋圆形或椭蹰形。 纳米银颗粒平均直径为11．9 nm，所有颗粒沿纤维的中轴线排列，部分呈椭圆形颗粒的长轴与纤维轴向一致。随银 溶腔凄量分数熊势离，其抗静电牲毖掇离。 关键谲静电缔丝；PA6；镶溶胶；蛮饪分布；抗静电性能 中圈分类号：TQ 342．11 文献标拣码：A Diameter distribution and antistatic property of PA6／Ag nanofiber WANG Hongbo，WANG Xi，HE Yanli，YU Hang，GAO Weidong，LI Jing，JIANG Lingling (研laboratory矽Eeo— Textiles(J／angnan u,a,M／ty)，Ministry铲Education，Wuxi。Jiangsu 214122，Ch／na) Abstract The nylon 6 nanofibre containing silver particles with different concentrations were prepared via electrospinning。The diameter distribution and morphology of nanofibres containing silver particles WaS analyzed by 8can electric microscope．and it was found that when the silver Inass fraction Wag in the range of 0．1％一 O．4％and the solution concentration was 10％一16％．the average diameter distributed from 70 nm to 90 nm。The diameter of the nanofibre reduced鹬the content of silver particles increased and increased as the solution concentration raised．The TEM images indicated that the silver particles were well— distributed in the nanofibers，showing round or elliptical，and the average diameter Was 1 1．9 nm．AU particles arranged along the nanofiber central axis line，and the long axis of some elliptical particles Was parallel to nanofiber central axis．The results showed that 118 the content of silver particles increased，the antistatic property obviously improved． Key words electrospinning；nylon 6：silver colloid；diameter distribution；antistatic property 通过静电纺丝法制备的纳米纤维具有较高比表 的金属盐或化合物方法得到含金属粒子的纳米纤 面积和高孔隙率等独特的性能。将金属纳米粒子加 维¨2|。含金属纳米纤维毡可以加快静电荷的散逸速 入聚合物溶液审，酉使纤维舆有电学、光学、催化、抗 笈，在空气褪对湿度极低酶条箨下选能发挥抗静电搀 菌等方面的性能¨_9J，故制胬功能性纤维的方法受 用，且抗静电作用持久【I引。已