RS-2000催化剂在2.2 Mt／a柴油连续液相加氢装置上的工业应用-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2014年第43卷第12期 PETR0CHEMICAL TECHN0L0GY ·l427· RS一2000催化剂在2．2 Mt／a柴油连续液相 加氢装置上的工业应用 董晓猛 (中国石化安庆分公司炼油二部，安徽 安庆 246000) [摘要]RS一2000~化剂为新型柴油超深度加氢脱硫催化剂，在中国石化安庆分公司2．2 Mt／a柴油连续液相加氢装置上进行工 业应用。该装置采用上流式反应器、热高压汽提分离器、循环油和补充氢分段注入等技术，特点是将含饱和氢的循环油分段 返回至反应器。经过催化剂装填、干燥、预硫化、初活性稳定等主要开工过程一次开车成功，并运行稳定。标定结果表明， 在处理量262 t／h、掺人焦化柴油26．2 t／ll、压力9．0 MPa、反应器人口温度353℃、循环比1．5的条件下，2．2 Mt／a柴油连续液相 加氢装置总能耗(以标准油计)为5．56 kg／t，硫脱除率平均为98．92％，氮脱除率平均为97．89％，能生产符合国Ⅳ标准的柴油 产品。 [关键词]RS一2000~化剂；超深度加氢脱硫；连续液相加氢；柴油 [文章编号]1000—8144(2014)12—1427—06 [中图分类号]TE624．431 [文献标志码]A Application of RS一2000 Catalyst in 2．2 Mt／a Continuous Liquid Phase Hydr0genation of Diesel DongXiaomeng (SINOPECAnqingBranchCompanyRefineryTwo，AnqingAnhui246000，China) [Abstract]The RS一2000 catalyst for ultra—deep hydrodesulfurization of diesel oil was applied in a 2．2 Mt／a installation for the continuous liquid phase hydrogenation of diesel oil in Sinopec Anqing branch．The running was successful after the catalyst was treated by loading，drying，presulfurizing and initial stabilizing．After the stable operation for five months，the calibration of the installation was carried out with full load．The results showed that the activity of the RS一2000 catalyst was high with good performances for desulfurization and denitrification．Under the conditions of feeding flowrate 262 t0a，coking diesel oil feeding flowrate 26．2 t／h，pressure 9．0 MPa，reactor inlet temperature 353℃ and circulation ratio 1．5，the energy consumption(based on the standard oil)，average sulfur rem