Ru-Cu／AlOOH催化苯选择加氢-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2013年第42卷第8期 PETR0CHEMICAL TECHN0LOGY ·843· Ru—Cu／AIOOH催化苯选择加氢 龚亚军，冯良荣，张淑青，邓成利，王 争，颜红阳 (中国科学院 成都有机化学研究所，四川 成都 610041) [摘要]采用共沉淀法制备了一系列不同(Cu)： (Ru)的Ru—Cu／A1OOH催化剂，利用XRD、TG—DTA、TEM、N，吸附一脱 附和XPS等方法对催化剂进行了表征，并对该系列催化剂进行了苯选择加氢反应测试。实验结果表明，在反应温度150℃、 氢气压力4．5 MPa、搅拌转速1 200 r／min、ZnSO 浓度0．40 mol／L的条件下，(Cu)： (Ru)=O．12的Ru—Cu／A1OOH催化剂具有 较高的活性和选择性，当反应17 minff~，环己烯收率达到最高值(46．6％)。Ru—Cu／A1OOH催化剂良好的活性和选择性主要归 结于活性组分的高度分散、载体良好的亲水性能以及助NCu对催化剂活性表面的调变作用。 [关键词]苯；环己烯；选择加氢；钌一铜／一水软铝石催化剂 [文章编号]1000—8144(2013)08—0843—06 [中图分类号]TQ 426．82 [文献标志码]A Ru—Cu／AIOOH Catalyst for Partial HydrOgenatiOn of Benzene Gong Yajun FengLiangrong，ZhangShuqing，Deng Chengli，WangZheng，YanHongyang (Organic Chemist~ofChengdu Institute，ChineseAcademy ofSciences，Chengdu Sichuan 610041，China) l Abstract J A series of Ru-Cu／A10OH catalysts with different Cu／Ru molar ratio were prepared by a coprecipitation method and characterized by means of XRD，TG—DTA，TEM，N2 physisorption- desorption and XPS．Their catalytic properties in the selective hydrogenation ofbenzene to cyclohexene were examined．The experimental results showed that under the conditions of ZnSO4 concentration 0．40 mol／L，reaction temperature 1 50 oC，hydrogen pressure 4．5 MPa，stirring speed 1 200 r／min and Ru—Cu／A1OOH with n(Cu)：n(Ru)0．1 2 as the catalyst，both the conversion of benzene and the selectivity to cyclohexene were high．When the reaction was conducted for 1 7 min，the cyclohexene yield reached the maximum of 46．6％．The high activity and selectivity of the Ru．CU／A1OOH catalysts are ascribed to the high dispersion of active compone