丙烯氧化制丙烯酸催化剂在万吨级工业装置上的应用-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2012年第41卷第3期 PETR0CHEMICAL TECHNOLOGY ·325· 丙烯氧化制丙烯酸催化剂在万吨级 工业装置上的应用 李雪梅，冯世强，焦 昆，秦春华，褚小东，邵敬铭 (上海华谊丙烯酸有限公司，上海 200137) [摘要]采用XRD和BET等手段对自制丙烯氧化制丙烯酸催化剂进行了表征；对该催化剂进行了小试、模试和10 kt／a工业装置 评价。试验结果表明，一段催化剂主要为CoMO ，Bi2Mo3Ol2，Bi2MoO6，FeMoO4，Co6Mo Bi¨Ox的晶相；二段催化剂主要为 MoO ，Mo O (Sb2O)M O (M=Mo，W，V)氧化物的晶相。小试评价结果为一段催化剂平均丙烯转化率98．1％、丙烯醛 和丙烯酸总收率92．3％、氧化碳总收率3．4％，二段催化剂平均丙烯醛转化率99．7％、丙烯酸收率97．9％、氧化碳收率1．6％；一 段和二段催化剂串联后，其模试评价的丙烯酸收率为88．8％，工业装置上运行时丙烯酸收率为88．9％。 [关键词]丙烯氧化；丙烯酸；复合氧化物催化剂 [文章编号]1000—8144(2012)03—0325—05 [中图分类号]TQ426 [文献标识码]A Industrial Application of the Catalyst for Oxidation of Prolylene to Acrylic Acid LiXuemei，FengShiqiang，JiaoKun，Qin Chunhua，ChuXiaodong，ShaoJingming (Shanghai HuayiAcrylicAcid Co．Ltd．，Shanghai 200137，China) l Abstract f The catalysts were characterized by means of XRD and BET，and their catalytic performance for oxidation of propylene to acrylic acid was evaluated through bench scale test，pilot scale test and 1 0 kt／a industrial test．The results showed that crystal phases of the first stage catalysts included CoMoO4，Bi2Mo3O12，Bi2MOO6，FeMoO4 and Co6Mol2Bi1 5O ，and crystal phases of the second stage catalysts included MoO3，Mo5O14 and(Sb20)M6O18(M=Mo，W，V)．The bench scale test indicated 98．1％ propylene conversion，92．3％ total yield of acrolein and acrylic acid，and 3．4％ carbon oxide yield for the first stage catalyst，and 99．7％ acrolein conversion，97．9％ acrylic acid yield and 1．6％ carbon oxide yield for the second stage catalyst．The acrylic acid yield could reach 88．8％and