偏钛酸型锂吸附剂的合成及吸附性能-中国有色金属学报.PDF

20 9 2010 9 Vol.20 No.9 The Chinese Journal of Nonferrous Metals Sep. 2010 1004-0609(2010)09-1849-06 ( 410083) TiO2 Li2CO3 Li2TiO3 H TiO 98.86%TiO Li TiO H TiO 2 3 2 2 3 2 3 H TiO XRD SEM H TiO 2 3 2 3 H TiO 2 3 LiOH 39.8 mg/g Langmuir Li2TiO3 O614.111 A Synthesis and adsorption property of H TiO type adsorbent 2 3 ZHANG Li-fen, CHEN Bai-zhen, SHI Xi-chang, MA Li-wen, CHEN Ya (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China) Abstract: H TiO type adsorbent was obtained by acid-modifying adsorbent precursor Li TiO , which was synthesized 2 3 2 3 by a simple solid-phase reaction between Li CO and TiO . The extraction rate of Li+ from Li TiO is 98.86%and while 2 3 2 2 3 almost no Ti4+ is extracted. TiO , Li TiO , H TiO and products of H TiO adsorbing Li+ were characterized by XRD and 2 2 3 2 3 2 3 SEM. The lithium adsorption properties were investigated by adsorption kinetics and adsorption isotherm. The kinetic data were studied by the pseudo-first-order and pseudo-second-order kinetic models. The rate constants of adsorption for these kinetic models were calculated. The results indicate that H2