储层伤害机理(国外英文资料).docVIP

储层伤害机理(国外英文资料) The mechanism of adsorption on solid-liquid interfaces is complex, and there may be several forces in certain adsorption processes. The polymers adsorption on solid-liquid interfaces is more complex. Reason is that there were significant differences in the size of the polymer molecules, and molecules of flexure and a certain number of active groups, the reactive group tends to adsorption on solid surface, and the adsorption of macromolecules with certain shape [22]. (2) mechanical trapping Mechanical capture the point at which the polymer molecules through a small pore flow constrained, molecular start winding, thread size bigger, outflow of the pore is greatly reduced, end up in the pore. Hydrodynamic trapping refers to polymer molecules through the larger pore due to stay in pore water dynamics factors, when the velocity changes that may flow out again (23-25). Factors that affect adsorption retention Since the solution of the solid adsorption, the size of the solute adsorption is not only related to the solute and the solid adsorbent, and the size of the relative affinity between solute and solvent. If the affinity between solute and solvent is large, the adsorption quantity of solute is small, whereas, the solute will be transferred to the surface of the solution and the adsorption quantity will be large. The lower the solubility in the solvent, the easier it will be adsorbed by the solids. Therefore, considering the factors affecting adsorption, must notice the adsorbent at the same time, solvent and solute the resulting effects in nature, all affect this affinity between, all can affect the adsorption. (1) the chemical structure and molecular weight of adsorption The adsorption behavior of polymer large molecules on solid surface is not only related to molecular weight, chemical structure, but also solvent. , because of the large polymer molecules move slower, to a solid surface in the pore diffusion is difficult, and adsorption of molecular ch