基础化学习题07(国外英文资料).docVIP

基础化学习题07(国外英文资料) Chapter 7 the rate of chemical reaction First page Problem resolution Student self-test questions The students surveyed themselves The answer is in the following chapter Problem resolution [TOP] Example 7-1 in the presence of acid in the presence of sucrose, the reading of the polarimeter is as follows: T/(min) 0 30 90 150 330 630 ? The at 46.57 41.00 30.75 22.00 2.75 10.00 18.75 This reaction is a first order reaction, which is the rate constant. The first order of the reaction, not only the concentration of the reactants, but the concentration of the concentration, if you have the concentration, you can replace the concentration. At the Angle of the polarization of the solution of sucrose, at t = 0 there is only sugar in the solution, at t =? It should disappear completely, and in the formula lncA = lncA0 minus kt, the ratio of cA0 to cA0 is a0 minus a? And the amount of this is at minus a infinity, so you can use the natural log of at minus a? = ln (a0 - a? Minus kt is the k at all times. And the solution 2 is by the graph method, lg at -a? If you plot the t, you get a line, the slope b is minus k over 2.303. T/min 0 30 90 150 330 630 The at - a? 65.32 59.75 47.50 40.75 21.50 8.75 Lg (at - a? 1.815 1.776 1.677 1.610 1.332 0.942 K = -2.303? B is equal to minus 0.00139, so K = 2.303? 0.00139 = 3.20? 10-3 min - 1 7-2 scientists have developed hematopoietic erythrocytes. The reaction of this red blood cell from the internal circulation is a first order reaction, with a half-life of 6.0 h. If an accident victims of red blood cells have been replaced by artificial red blood cells, arrived at the hospital after 1.0 h, then the artificial red blood cells in the body of the input of artificial red blood cells score is? The solution to the first order reaction, According to the formula of the first order rate, the score of blood cells in the blood cells is done. Example 7-3 urea hydrolysis reaction is CO (NH2) 2 plus H2O? 2 nh3 + CO2 25 ° C without the enz