细胞色素c综述(国外英文资料).docVIP

细胞色素c综述(国外英文资料) 2 Niki irreversible adsorption model Niki [11] using ac impedance method such as reflection method, ultraviolet, visible, infrared reflection method to study the son derivatives of 4 - pyridine basis promoter in the role of cyt c - transfer, put forward the existence of at least three types of adsorption: The first type: cyt-cs adsorption ability is stronger than the promoter, and when both of them coexist in the solution, cyt-c preferentially adsorbs on the surface of the metal electrode. If the accelerator is pre-attached to the electrode surface, it will be easily replaced by cyt-c in the cyt-c solution. The second type: cyt c adsorption ability and promoter, the two competing adsorption, so there are two kinds of adsorption in the form of cyt c, some adsorbed on the electrode surface directly, while some adsorption on the promoter molecules on the surface of the electrode. Thus, there are two types of REDOX reactions: cyt-c, which adsorbs on the gold electrode, and cyt-c, which is attached to the promoter. Because of the interaction between cyt-c and promoters, cyt-c is much less deformable on the surface of the electrode than the deformation on the bare electrode. A third type: the adsorption capacity of the accelerator is stronger than cyt c, can be strongly adsorbed on the electrode surface, cyt c adsorption or key for these molecules on the accelerator, maintain its natural shape and electron transfer. 2 papers idea As described above, the cyt-c is a simple structure that extracts and provides an important physiological function in the body. It is still a challenging and meaningful work to study the direct electron transfer in biology and extend its application in analytical chemistry. On the basis of systematic literature research, we chose to study cyt c - direct electrochemical behavior and expand its application in analytical chemistry research goal, the basis of systematically research work. First, use PFV to study the transmission of t