碱性Li3PO4催化剂的失活及再生.pdfVIP

学兔兔 石 油 化 工 2015年第44卷第4期 PETR0CHEMICAL TECHN0L0GY ·453· 碱性Li3 PO4催化剂的失活及再生 李 浩，李 菲，周 璇，马卫华，钟 秦 (南京理工大学化工学院，江苏南京210094) 【摘要]研究了气相环氧丙烷(PO)异构化制烯丙醇反应中碱性Li PO 催化剂的失活及再生。实验结果表明，在280℃下反应 54 h后，因催化剂表面覆盖大量含氢碳物种引起失活，采用煅烧法、水蒸气洗涤法去除催化剂上的积碳，可使催化剂得到再 生。通过XRD、FTIR、原位DRIFT、BET、TG、MAS NMR等手段对催化剂进行表征发现，失活Li PO 催化剂的比表面及孔 体积均下降，但催化剂晶型未发生改变，也无新物相生成。积碳分解温度为300～500 oC，在350℃下积碳分解所需时间为 40～50 min。煅烧法再生的Li PO 催化剂上PO转化率为90．7％，烯丙醇选择性为89．8％，与新鲜Li PO 催化剂的活性相近。 [关键词]环氧丙烷；异构化；烯丙醇；磷酸锂催化剂；积碳；失活；再生 [文章编号]1000—8144(2015)04—0453—06 [中图分类号]TQ 426 [文献标志码]A Deactivation and Regeneration of Basic Lithium Phosphate Catalyst Li Hao，Li Fei，Zhou Xuan，Ma Weihua，Zhong Qin (Department of Chemical Engineering，Nanjing University of Science and Technology，Nanjing Jiangsu 210094，China) [Abstract]The deactivation and regeneration of basic lithium phosphate catalyst used in the isomeri— zation of propylene oxide to allyl alcohol were studied．The results showed that the basic lithium phos— phate catalyst deactivated after the reaction at 280 oC for 54 h which was due to carbon deposition con— ， taining H element．The carbon deposition could be removed by washing with steam or calcining．The flesh，deactivated and regenerated catalysts were characterized by means of XRD，FTIR，in—situ DRIFT，BET，TG and MAS NMR．The specific surface area and pore volume of the deactivated cata— lyst decreased without the formation of new phase．The decomposition temperature of the carbon depo— sition was in the range of 300—500 oC and at 350 oC the decomposition ne