轻质石脑油分裂的研究及工业应用.pdfVIP

学兔兔 石 油 化 工 2015年第44卷第8期 PETR0CHEMICAL TBCHN0LoGY ·985· 轻质石脑油分裂的研究及工业应用 韩 峰，王文彬，孟宪谭 (中国石化 齐鲁分公司，山东 淄博 255400) [摘要]针对中国石化齐鲁分公司800 kt／a乙烯装置原料种类多、物性各异的现状，利用SPYRO软件模拟工业裂解炉的工艺条 件，对不同石脑油(NAP)原料的裂解性能进行了对比评价，根据原料物性及主要裂解产物收率，提出了互供NAP分裂的优化 方案，研究了分裂前后不同原料裂解的适宜工艺操作条件，对比了主要裂解产物收率的变化，考察了互供NAP分裂对乙烯装 置经济效益及工业裂解炉运转周期的影响。工业运行结果表明，互供NAP分裂可有效提升乙烯装置的技术经济性，主要裂解 产物收率大幅提高，以投料量1 520 kt／a计，三烯(乙烯、丙烯、丁二烯)收率提高了0．64百分点，副产物收率降低了0．85百分 点，实现年增效1 800余万元，具有良好的工业应用效果。 [关键词]乙烯；裂解原料；轻石脑油；分裂；三烯收率 [文章编号]1000—8144(2015)08—0985—04 [中图分类号]TQ 221．211 [文献标志码]A Research and Commercial Application of Light Naphtha Cracking Han Feng，Wang Wenbin，MengXiantan (Qilu Branch Co．，SINOPEC，Zibo Shandong 255400，China) [Abstract]Aimed at many kinds of naphtha feedstock with different properties in the 800 kt／a ethylene unit of Qilu Branch Co．，SINOPEC，the cracking performances of the naphtha in cracking fumace were simulated by means of the SPYRO software．An optimization method was established for that the light naphtha and heavy naphtha were separately stored and cracked．The optimum operating conditions were investigated before and after the separate storing and cracking，and the yields of triolefin as main crackates were compared．The effects of the separate storing and cracking on the economic efficiency and the running period of the cracking furnace were researched．The commercial application results showed that the separate cracking of the self-produced naphtha could increase the economic efficiency of the ethy lene unit．Based on the feedstock of 1 520 kt／a，the triolefi