黄河中下游流域表层土壤中多氯联苯的残留特征.pdfVIP

中国环境科学 2016,36(9) ：2741~2748 China Environmental Science 黄河中下游流域表层土壤中多氯联苯的残留特征 * 卢 双,张 旭,裴 晋,姚 宏 ,于晓华 (北京交通大学土木建筑工程学院,北京 100044) 摘要：采用气质联用仪(GC-MS)对黄河中下游流域 18 个国家控制断面处表层土壤(0~15cm)样品中的多氯联苯含量进行测定,分析其残留 特征、可能的污染源和生态风险.结果表明,黄河中下游表层土壤中∑PCBs 变化范围为 0.43~39.83ng/g dw,均值为 3.72ng/g ,和其他地区研究 结果相比,黄河中下游流域表层土壤中 PCBs 含量水平较低.类二 类 PCBs 的毒性当量 DL-TEQ 变化范围为 1.85~27.22pg/g dw,均值为 15.24pg/g dw,远低于其他国家相应的限值,极少存在生态风险. PCB18、PCB33 、PCB49 、PCB44 、PCB52 的检出率和残留量均比较高,是黄 河中下游流域表层土壤中的优势污染物.二氯联苯、三氯联苯和四氯联苯是主要的同族体,分别占总量的 10.71%.13.48%、63.43%,说明黄 河中下游流域表层土壤中主要是低氯联苯污染.主成分分析表明黄河中下游流域表层土壤中 PCBs 主要是来自 Aorclor1242 、1248、1254、 1260 系列 PCBs 产品和国产变压器油的混合污染源. 关键词：多氯联苯；黄河流域；表层土壤；残留特征 中图分类号：X53 文献标识码：A 文章编号：1000-6923(2016)09-2741-08 Residual characteristics of polychlorinated biphenyls in surface soil of the Middle and Lower Reaches of the Yellow * River. LU Shuang, ZHANG Xu, PEI Jin, YAO Hong , YU Xiao-hua (School of Civil Engineering and Architecture, Beijing Jiaotong University, Beijing 100044, China). China Environmental Science, 2016,36(9)：2741~2748 Abstract ：The residual characteristics of polychlorinated biphenyls (PCBs) in 18surface soil (0~15cm) samples collected from the Middle and Lower Reaches of the Yellow River were analyzed by GC-MS. The results showed that the concentrations of total PCBs in surface soil ranged from 0.43 to 39.83 ng/g dry weight (ng/g dw), with an average value of 3.72 ng/g dw, and the average PCBs level in this study was in a comparatively low level when compared with those in others regions. The toxic equivalency concentrations of dioxin-like PCBs (DL-TEQ)in surface soil ranged from 1.85 to 27.22 pg/g dw, with an average value of 15.24 pg/g dw. The DL-