PET_PP共混体系的熔融及非等温结晶行为.pdfVIP

理论与研究 Vol.35 No.1 (Sum.177) January 2007 文章编号：1005-3360(2007)0 1-0028-04 PET/PP共混体系的熔融及非等温结晶行为 Melting and Non-isothermal Crystallization Behavior of PET/PP Blend (1) 张义盛，吴德峰 ，曹 健，张 明，吴兰峰 Zhang Yisheng, Wu Defeng, Cao Jian, Zhang Ming, Wu Lanfeng - 扬州大学化学化工学院，江苏扬州225002 - School of Chemistry Chemical Engineering, Yangzhou University, Yangzhou 225002, China 用熔融共混法制备了聚对苯二甲酸乙二醇酯 （ ）聚丙烯 （ ）复合材料。对复合体系的形态结构、 摘 要 : PET / PP 熔融及非等温结晶行为进行了研究。结果表明：两相界面或 相对 结晶无明显的异相成核效应； PP PET 当 为连续相时，已结晶的极性 粒子对 的异相成核作用较为明显；而当 为分散相时，固态的 PP PET PP PP 在一定程度上阻碍了 分子链的运动，促使 结晶均相成核趋势增加。与纯 或 相比，共混 PET PP PP PET PP 体系中两组分结晶的完善程度都有所下降。 Abstract : The immiscible poly(ethylene terephthalate)/polypropylene blend (PET/PP) was prepared via melt blending. The morphological structures and melting properties as well as non-isothermal crystallization behavior of blend were investigated. The results show that the phase interface and/or PP phase nearly has no apparent heterogeneous nucleation effect on the crystallization