以单水铝石(Boehmite)制造a-氧化铝微粒粉末的研究.PDF

以單水鋁石(Boehmite)製造a-氧化鋁微粒 粉末的研究* Fabricating Nano-scaled a-Alumina Powders Using Boehmite as the * Raw Material 1 2 2 1 2 2 F.S. Yen R.J. Yang P.C. Yu B o eh m it e a - T h i s r ep or t elu c i d at e s t h r e e i m p or t a n t Boehmiteboehmite information of fabricating specified nano-scaled gδθ a a- a-phase alumina (a-Al O ) powders using θ-phase 2 3 θa alu m in a (q-A l O ) a s th e st ar t in g m at er ial . 1. 2 3 dθс ~30 nm boehmite The θ-to a-phase alumina phase tr an sformation θ- (θ-a-A l O ) en cou nt er s t h e cr it ical si z e of 2 3 a- phase tran sformation , being ~30 nm (d c). Then θ- θ-Al2O3 particles with sizes smaller and larger than a ~30 nm would lead to different thermodynamic growth routes after a-Al O nuclei are formed. The 2 3 ds 80~ 100 nm a former per form s stable sizes by the coalescence 80~ 100 nm θ- mechanism. a-crystallites behave stable as the size dθс ~30 50 nm θ- exceeds 80 to 100 nm. While the latter can be stable a- as the sizes are larger than ~30 nm . 2 . A qu asi homogeneou s phase transformation is required to 80- 100 nm a- avoid the occurrence of first come and first coarsen 30 nm a- phenomena. 3. Domain restriction or limiting the