中和—混凝法处理三氯氢硅尾气洗涤废水.pdfVIP

工业水处理 第 31 卷第 9 期 Vo1.31 No.9 2011 年 9 月 lndustrial Water Treatmpnt 立μ21」 中和一混凝法处理三氯氢硅尾气洗涤废水 曾凤春 (四川理工学院化学与制药工程学院，四川自贡 643ω0) [摘要]采用中和-混凝法处理三氯氢硅生产过程中的尾气洗涤废水。经实验确定最佳工艺条件:中和后的悬 浮液 pH 为 7-9 ，混凝剂聚合氯化铝的投加质量浓度为 30 mg/L，快速搅拌 30 min ，慢速搅拌4O min ，静置 ωmin。实 验结果表明:在最佳工艺条件下对废水进行处理，出水无色透明，浊度和囚的去除率均在 97%以上，Si0 去除率在 2 92%以上，可全部返至洗涤系统循环使用。 [关键词]中和;混凝;三氯氢硅;废水处理 [申图分类号] X703 [文献标识码] A [文章编号] 1 ∞5-829X(2011 )09-∞67-03 Treatment of tail gas washing wastewater from SiHCI3 production by neutralization-coagulation process Zeng Fengchun (College ofChemica1 and Phannaceutic a1 Engineering ,Sichuan lnstitute ofScience and Technology ,Zigong 643000 ,China) Abstract: Neutralization-coagulation process has been applied to the treatment of tail gas washing wastewater from 5iHCl3 production. The optimum conditions are as follows: the pH of the suspending liquid after neutralization is 7- 9 ,the mass concentration of coagulant polyaluminum chloride added dosage is 30 mgIL, fast stirring time is 30 min , slow stirring time is 40 min and standing time 60 min. The results show 由at the effluent water is colorless and trans- parent ,its removal rates of S5 ,turbidity and Si02 缸e 97% ,97% and 92% or more respectively ,and the water can 肥 turn to the washing system and be recycled completely. Key words: neutralization; coagulation; trichlorosilane ;wastewater treatment 三氯氢硅(5iHCI ) 是重要的有机硅单体，可用 3 的尾气洗涤废水，其水质为