甲基丙烯酸对聚合物乳胶粉再分散性影响机理-whxb.PDF

物理化学学报(Wuli Huaxue Xuebao) December Acta Phys. ⁃Chim. Sin., 2010, 26(12) ：3237-3242 3237 [Article] 甲基丙烯酸对聚合物乳胶粉再分散性影响机理 * 司徒粤 周利庄 蓝仁华 夏正斌 陈焕钦 (华南理工大学化学与化工学院, 广州 510640) 摘要： 采用半连续种子乳液聚合法, 以甲基丙烯酸(MAA)为壳层亲水功能单体, 合成了丙烯酸酯原乳液, 并通 过喷雾干燥法制得具有可再分散性的聚合物乳胶粉. 讨论了原乳液粒子粒径随pH 值和MAA 量的变化关系; 重 点研究了MAA 量对乳胶粉水分散液稳定性、再分散乳液zeta 电位、乳胶粒粒径分布及乳胶粉内部微观形貌的 影响, 并分析其作用机理. 研究结果表明: 原乳液粒子粒径随pH 值的增大逐渐增大, 且MAA 含量越高, 粒径增 幅越大; 随MAA 量增加, 再分散液稳定性增强, zeta 电位绝对值增大, 平均粒径逐渐变小, 乳胶粉再分散性显著 改善. 透射电子显微镜(TEM)结果显示: 当MAA 含量较高时, 乳胶粉内部出现较大孔径的中空微孔结构. 中空 微孔结构提供水分向乳胶粉内部扩散通道, 因而优化其水分散性, 再分散乳液的“绒毛结构”与较高的zeta 电位 赋予其优异的分散稳定性. 关键词： 甲基丙烯酸; 可再分散性乳胶粉; 稳定性; 中空聚合物粉末 中图分类号： O648 Influencing Mechanism of Methacrylic Acid on the Redispersion Properties of Redispersible Polymer Powders SITU Yue* ZHOU Li-Zhuang LAN Ren-Hua XIA Zheng-Bin CHEN Huan-Qin (School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China) Abstract ： Acrylic polymer emulsions were synthesized by semi-continuous seeded emulsion polymerization and the corresponding redispersible polymer powders were prepared by spray drying. Methacrylic acid (MAA) was used as the hydrophilic shell monomer. The influences of the amount of MAA on the average particle size of the original emulsion, the dispersion stability, zeta potential, and size distribution of the redispersion emulsion were