第2章逐渐聚合习题参考谜底(国外英文资料).docVIP

第2章逐步聚合习题参考答案(国外英文资料) The second chapter, condensation polymerization and stepwise polymerization reaction questions 1. terms: gradual polymerization, condensation polymerization, functional groups and other activities; linear polycondensation; Type Polycondensation; gel point; conversion rate; reaction degree. Answer: Stepwise polymerization of monomers into polymers is a step by step process, which is a gradual increase in the interaction of monomers and functional groups. Condensation polymerization - a continuous, repeated condensation reaction between monomers with two or more functional groups, two. Functional groups and other activities - within a certain degree of polymerization, the activity of functional groups is independent of the molecular weight of polymers. Linear polycondensation - the monomers participating in the reaction all contain two functional groups, and the molecules formed in the reaction increase in two directions, resulting in a reaction of linear polycondensation. Single dimensional polycondensation in response to at least one monomer containing functional groups of more than two, and the average functionality is greater than 2, the macromolecular reaction in three directions of growth, this kind of reaction type structure of polymers. Gel point - the critical degree of reaction occurring at the beginning of the gel. Conversion - the fraction of the monomer involved in the reaction was the fraction of the initial monomer Degree of reaction the number of groups involved in the reaction is the fraction of the starting group. 3. by dicarboxylic acid and hexamethylenediamine Moore synthesis of nylon 6,6. The equilibrium constant K=432 for the polymerization is known. If the polymer is polymerized at 200, how much should the water content in the reaction system be controlled? Solution: The substitution of =200 and K=432 into this formula is available: Answer: the water content in the reaction system should be controlled to be 0.0108 mol/L. 4