改性的Ni基催化剂上CO甲烷化性能的研究.pdfVIP

学兔兔 石 油 化 工 · 260· PETR0CHEMICAL TECHN0LOGY 2012年第41卷第3期 改性的Ni基催化剂上CO甲烷化性能的研究 王 鑫，郭翠梨，张俊涛，詹吉山 (天津大学 化工学院，天津 300072) [摘要]采用浸渍法制备了Ni0／Al O ，NiO／TiO：一A12O3，NiO—La O，／A1203，NiO—La203／TiO2一A12O3催化剂，考察Y4种催化剂 的CO甲烷化性能，并利用TG+DTG方法表征催化剂表面的积碳量。实验结果表明，NiO／TiO2一AI O，，NiO—La／O ／A12O ，NiO— La，O ／TiO 一A1 O 催化剂，~1]TiO2和La O 改性的NiO／A12O 催化剂的CO甲烷化反应活性均有所提高，其中NiO—La：03／TiO 一 A1，O 催化剂的活性、稳定性和抗积碳能力最好；采用NiO—La：0 ／TiO 一A1 0 催化剂，cow烷化反应的适宜条件为：反应 温度450℃、反应压力1．5 MPa、GHSV=10 000 h。。，在此条件下，CO转化率为99．5％，CH4收率和选择性均为98．1％。 [关键词]一氧化碳甲烷化；镍基催化剂；NiO—La2O3／TiO2一A1203催化剂 『文章编号]1000—8144(2012)03—0260—05 [中图分类号]TQ 426 [文献标识码]A Catalytic Performance of Modified Ni Catalyst in CO Methanation WangXin，Guo Cuili，ZhangJuntao，Zhan Jishan (School ofChemical Engineering andTechnology，TianjinUniversity，Tianjin 300072，China) [Abstract]A series of catalysts，namely NiO／A12O3，NiO／TiO2-A12O3，NiO—La2O3／Al2O3 and NiO—La203／TiO2一A12O3 were prepared by impregnation．The catalytic performances of the catalysts in CO methanation were investigated．The carbon depositions on the catalysts were analyzed by means of TG．DTG．The results showed that the activities of NiO／TiO2一Al203，NiO—La203／Al203 and NiO— La203／TiO2-A12O3 catalysts for CO methanation were higher than that of NiO／A12O3 catalyst，among which NiO—La2O3／TiO2一A12O3 catalyst showed the highest activity，stability and anti-coking capacity． Under the appropriate reaction conditions of NiO-La2O3／TiO2-Al2O3 as catalyst，reaction temperature 450 oC，pressure 1