本体型Ni-Mo催化剂用于萘加氢合成十氢萘.pdfVIP

学兔兔 石 油 化 工 PETRoCHEMICAL TECHNoLoGY 2015年第44卷第7期 本体型Ni—Mo催化剂用于萘加氢合成十氢萘 申宁宁，薛书书，殷长龙，程文豪，王立卓，刘晨光 (中国石油大学(华东)重质油国家重点实验室 CNPC催化重点实验室，山东 青岛 266580) [摘要]采用水热合成法制备本体型Ni—Mo，Ni—W，Ni—Mo—w催化剂，用于萘加氢合成十氢萘。采用XRD和BET方法对催化 剂进行表征。考察催化剂种类、Ni与Mo摩尔比和反应条件对萘加氢性能的影响。实验结果表明，Ni—Mo催化剂的比表面积较 大，金属活性位分布较均匀；与Ni—w和Ni—Mo—w催化剂相比，Ni—Mo催化剂的萘加氢活性最高且活性稳定性高；Ni—Mo催 化剂的活性组分为钼酸镍铵晶相，且具有较好的孔道结构。采用Ni与Mo摩尔比为1．5的Ni—Mo催化剂，萘加氢适宜的反应条 件为：200 oC、4 MPa，液态空速2 h～、氢油体积比3o0，在此条件下萘的转化率达99．8％，十氢萘的选择性达99．9％，十氢萘 产物中反一十氢萘的含量接近90％(W)。 [关键词]本体型Ni—Mo催化剂；萘加氢；十氢萘 [文章编号]1000—8144(2015)07—0846—06 [中图分类号]TQ426．82 [文献标志码]A HydrogenatiOn of Naphthalene to Decalin on Sulfurized Massive Ni—Mo Catalysts Shen Ningning，Xue Shushu，M，l Changlong，Cheng Wenhao，WangLizhuo，Liu Chenguang (State Key Laboratory ofHeavy Oil Processing，CNPC Key Laboratory ofCatalysis，China University ofPe~olettm(Huadong) Qingdao Shandong 266580，China) l Abstract J A serious of massive Ni—Mo，Ni-W and Ni—Mo—W catalysts were prepared through hydrothermal synthesis，and were characterized by means of XRD and BET．The catalysts were used in the hydrogenation of naphthalene to decalin．The effects of catalyst types，Ni／Mo mole ratio and reaction conditions on the conversion of naphthalene and the selectivity to decalin were investigated． Among the catalysts，the Ni—Mo catalysts showed the highest activity in the hydrogenation and high