氟烷基化胺基硅油合成及织物增深整理应用.pdfVIP

中文摘要 氟烷基化胺基硅油合成及织物增深整理应用 深效果。将氟烷基改性氨基硅油与纳米 SiO2 颗粒复配整理取得了良好的增深效果， K/S 值提升率为38.15% 。 关键词：合成，增深整理，改性氨基硅油，氟烷基烯酸酯 作 者：许 燕 指导老师：李战雄 教授 II Synthesis of Fluoroalkyl-modified Amino Silicone Oil and its Application on Fabric Deepening Finishing Abstract Synthesis of Fluoroalkyl-modified Amino Silicone Oil and its Application on Fabric Deepening Finishing Abstract In this dissertation, fluoroalkyl modified aminosilicone oil was synthesized using fluoroalkyl alkenylcarboxylic ester as the modifier agent. The reaction was carried out between unsaturated double bond (C=C) of fluoroalkyl alkenylcarboxylic ester and primary amino groups of amino silicon oil side-chain via Michael addition reaction. The product was emulsified to obtain a homogeneous emulsion and then coated onto fabric to increase the color depth of fabrics. The mechanical of this performance was to reduce the refractive index of amino silicone oil through modification with fluoroalkyl groups. Three kinds of fluoroalkyl alkenylcarboxylic esters, such as hexafluorobutyl acrylate, bis(1H, 1H, 2H, 2H-Tridecafluorooctyl)methylenesuccinate and 1H, 1H, 2H, 2H-Tridecafluorooctyl-1- acrylate, were used as modifier agents and three different fluoroalkyl modified aminosilicone oils were obtained. A series of fluoroalkyl modified amino silicone oils with different fluorine content were prepared by controlling the molar ratio of the reactants. In addition, nano-SiO2 particle was prepared by using tetraethyl orthosilicate as the silicon source, ethyl alcohol as the dispersing agen