溶剂控制组装三核铜簇成零维到三维结构配合物的合成与分子识别.pdfVIP

Abstract In this work, we choose triethanolamine(teaH ), N-methyldiethanolamine(MedeaH ) and 3 2 4,4‟-oxy-bis(benzoate) (oba) as the mixed ligands to explore the different alcoholthermal reactions.Eight novel metal coordination polymers based on such ligands were obtained and further characterized by single crystal X-ray diffraction, thermogravimetric analysis and gas adsorption and desorption studies. The eight metal coordination polymers are as follows: Cu (teaH ) (oba) (MeOH) (1), Cu (teaH ) (oba) (EtOH) (2), Cu (teaH ) (oba) ∙(n-PrOH) (3), 3 2 2 2 2 3 2 2 2 2 3 2 2 2 Cu (teaH ) (oba) (4), Cu (teaH ) (oba) (H O) (5), Cu (MedeaH) (oba) (MeOH) (6), 3 2 2 2 3 2 2 2 2 2 3 2 2 2 Cu[Cu (Medea) (oba) ]∙(solvent) (7), and [Cu (MedeaH) (oba) (H O)]∙(n-PrOH) (8). 3 2 2 x 3 2 2 2 2 The structures of 1-8 exhibit two types of extensible modes (Mode I for 1, 2, 3, 7, 8 and Mode II for 4, 5, 6) to Cu SBUs. In 1-8, the trinuclear copper SBUs (Cu ) is furnished via the 3 3 synergistic coordination of two organic ligands with metal centres. Compounds 1 and 2 feature 0D molecular structures in which two strong hydrogen-bonding interactions