满山香子有效成分的提取与分离.pdfVIP

以及参考对照文献而确定，它们分别为水杨酸甲酯 2-O- β-D-葡萄糖苷和水杨酸甲酯 2-O- 1 13 β-D-木吡喃糖基(1→6)- β-D-葡萄糖苷。通过对化合物 15 的UV 、 H NMR 、 C NMR、 DEPT 、H-H COSY 、HSQC 、HMBC 、NOESY 和 MS 等谱图的解析，确定其结构，检索 SciFinder Scholar 数据库，确定为新化合物，命名为 4β,6α－二甲基－雅槛蓝－7(11),8(9) － 二烯－12,13(4α,6α) －二内酯。余下的5个化合物的结构，尚需进一步做相关的测定。 在分离得到的23个化合物中，确定了18个化合物的结构，除β-谷甾醇外，均为首次 从该植物中分离得到。 关键词：五味子科；满山香；满山香子；化学成分；4β,6α－二甲基－雅槛蓝－7(11),8(9) －二烯－12,13(4α,6α) －二内酯 Extraction and Isolation of the Chemical Constituents of the Seed of Schisandra propinqua (Wall) Hook.f.et Thoms. Research Interest: Natural Organic Chemistry Major: Organic Chemistry 2003 Grade Author: Li Fu Supervisor: Li Jun Abstract Schisandra propinqua(Wall)Hook.f.et Thoms ，a member of schisandraceae, mainly distributing in Yunnan and Guangxi province in China, was found in the second half of the last century and has lots of pharmacology effects, including antiheptits, antitumor, anti-HIV and platelet- activating factor antagonistic activities according to the references. It was reported that Manshanxiang Complex, a herbal medicine preparation in which the roots and stems of Schisandra propinqua (Wall)Hook.f.et Thoms are a major component, was used for treatment of lung cancer. Up to now, there were not any reports about the studies on the seed of schisandra propinqua (Wall)Hook.f.et Thoms. In order to understand the chemical constituents in it, the chemical constituents of the seed of schisandra propinqua(Wall)Hook.f.et Thoms were studied in this dissertation. This dissertation composes of two chapters. The first chapter is a