三聚氰胺甲醛乙二胺四草酰乙酸螯合树脂碳纤维复合材料的制备及应用研究.pdfVIP

三聚氰胺- 甲醛- 乙二胺四草酰乙酸螯合树脂/碳纤维复合材料的 制备及应用研究 摘 要 本文以酸化碳纤维为基体、在其上共价修饰了前驱体乙二胺，进而接枝了 三聚氰胺- 甲醛- 乙二胺四草酰乙酸螯合树脂，获得了功能化碳纤维复合材料 (C/B/A/CF) 。通过场发射扫描电子显微镜(FE-SEM) 、X-衍射光电子能谱(XPS) 和红外光谱(FT-IR)表征了该复合材料的特性。 该复合材料对Ni2+ 的吸附热力学及动力学研究显示 ：C/B/A/CF 对 Ni2+ 的 吸附过程是吸热自发进行的，符合准二阶动力学模型，为单分子层吸附。研究 利用三聚氰胺- 甲醛- 乙二胺四草酰乙酸螯合树脂/ 碳纤维复合材料，于化学镀镍 废液中先行吸附Ni2+ ，再原位电化学沉积Ni2+ ，制备了纳米镍/ 碳纤维催化剂 (Ni/ CF) ，该催化剂对乙醇具有良好的电催化作用。 关键词：三聚氰胺– 甲醛– 乙二胺四草酰乙酸螯合树脂；碳纤维的功能化衍生； 化学镀镍废液；镍回收；电催化 I Preparation and Application of Melamine-Formaldehyde-Tetraoxalyl Ethylenediamine Chelating Resin / Carbon Fiber Composite Material ABSTRCT In this work, a useful complex material, melamine-formaldehyde-tetraoxalyl ethylenediamine chelating resin/carbon fiber composite material was fabricated by compound synthesis of electrochemistry and organic chemistry. The process as follow: firstly ethylenediamine was prior covalently modified at carbon fibers using a constant potential; secondly tetraoxalyl ethylenediamine was inoculated at the carbon fibers by amidation reaction; Then melamine, formaldehyde and tetraoxalyl ethylenediamine were polymerized at the carbon fibers (C/B/A/CF). The morphology and structure were characterized by various methods including field emission scanning electron microscope (FE-SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and infrared spectrum (FT-IR). Both adsorption properties of kinetic and thermodynamic of the material towards Ni2+ were studied, respectively. The adsorption process belonged to pseudo-second order model; it was mainly monolaye