锂离子电池容量衰减机理和副反应-翻译个人翻译的外文文献.doc

Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries 锂离子电池容量衰减机机理和副反应 Pankaj Arorat and Ralph E. White* 作者：Pankaj Arorat and Ralph E. White* Center For Electrochemical Engineering, Department of Chemical Engineering, University of South Carolina,Columbia, South Carolina 29208, USA 美国，南卡罗来纳，年哥伦比亚29208，南卡罗来纳大学，化学工程系，中心电化学工程 ABSTRACT The capacity of a lithium-ion battery decreases during cycling. This capacity loss or fade occurs due to several different mechanisms which are due to or are associated with unwanted side reactions that occur in these batteries. These reactions occur during overcharge or overdischarge and cause electrolyte decomposition, passive film formation, active material dissolution, and other phenomena. These capacity loss mechanisms are not included in the present lithium-ion battery mathematical models available in the open literature. Consequently, these models cannot be used to predict cell performance during cycling and under abuse conditions. This article presents a review of the current literature on capacity fade mechanisms and attempts to describe the information needed and the directions that may be taken to include these mechanisms in advanced lithium-ion battery models. Introduction The typical lithium-ion cell (Fig. 1) is made up of a coke or graphite negative electrode, an electrolyte which serves as an ionic path between electrodes and separates the two materials, and a metal oxide (such as LiCoO2, LiMn2O4, or LiNiO2) positive electrode. This secondary (rechargeable) lithium-ion cell has been commercialized only recently.Batteries based on this concept have reached the consumer market, and lithium-ion electric vehicle batteries are under study in industry.The lithium-ion battery market has been in a period of tremendous growth ever since Sony introduced the first commercial cell in 1990.With energy density exceeding 130 Wh/kg (e.g., Matsushita CGR 17500) and cycle life of more than 1000 cycles (e.g., Sony 18650)