PZT陶瓷粉体的水热合成介绍.PDF

第27 卷 第5 期 无 机 材 料 学 报 Vol. 27 No. 5 2012 年5 月 Journal of Inorganic Materials May, 2012 文章编号: 1000-324X(2012)05-0507-06 DOI: 10.3724/SP.J.1077.2012.00507 PZT 陶瓷粉体的水热合成 朱孔军, 朱仁强, 董娜娜, 顾洪汇, 裘进浩, 季宏丽 ( 南京航空航天大学 机械结构力学及控制国家重点实验室, 南京 210016) 摘 要: 利用水热法合成了单相、立方体形貌且平均颗粒尺寸在 1 μm 的锆钛酸铅(PZT)陶瓷粉体. 研究了碱度、反 应时间对最终产物的影响, 着重研究了不同碱度下 Pb 缺失的补偿问题. 结果表明: 碱度对最终 PZT 产物 A 位 Pb 离子的固溶程度有着重要的影响. 碱度越高, A 位缺失的 Pb 离子就越多. 原料中适当的 Pb 过量能够有效补偿 Pb 离子的缺失, 碱度越高, 所需添加的Pb 离子的过量程度也就越高. 但过多的Pb 离子加入量会导致最终产物中出现 第二相. 关 键 词: PZT 粉体; 水热合成; 铅过量 中图分类号: TF125 文献标识码: A PZT Powders Synthesized by Hydrothermal Method ZHU Kong-Jun, ZHU Ren-Qiang, DONG Na-Na, GU Hong-Hui, QIU Jin-Hao, JI Hong-Li (State Key Laboratory of Mechanics and Control of Mechanical Structures, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China) Abstract: Lead zirconate titanate (PZT) powders with single-phase, cubic morphology and average size of 1 μm were synthesized using hydrothermal methods. Effects of KOH concentration, hydrothermal treatment time and Pb excess were investigated. The results show that KOH concentration has an important influence on the solid solubility of Pb ion in A-site of PZT perovskite structure. The concentration of Pb2+ vacancies increased with the increase of OH−con- centration. However, this kind of deficiency could be compensated by adding more Pb ions in the raw materials, and more Pb ions were needed to add with higher alkaline conce