催化剂润湿钝化.pptxVIP

1;Wetting is not a chemical reaction 润湿不是化学反应 Heat is released when oil passes through dry catalysts. 当油接触催化剂时，放热 Wetting has caused exotherms of 100?F (55?C) per catalyst bed 润湿大约会使每床层温升55C The first oil to hit the catalyst gets hotter and hotter. 油的初次接触催化剂会放热剧烈 After the heat wave passes, the catalyst is cooled by gas and colder oil. 热流过去后，催化剂会被气体和冷油逐渐冷却 Without cooling between beds, high temperature goes into the next beds. 如果床层间无冷却，高温会迭加到下一床层;Catalyst Wetting Temperature Waves 催化剂润湿温波;Catalyst Wetting Temperature Waves 催化剂润湿温波;Normal control 正常控制 Feedback 反馈控制 Bed outlet T causes controller to change the Bed Inlet T 床层出口温度升高，控制器会改变床层入口温度 It takes 3 to 5 min for a change to reach the Bed Outlet 3-5分钟后，床层出口温度会显现效果 BUT: Wetting heat waves travel to the next bed in 1 minute 但是：润湿的温波通过一个床层，一般小于1分钟 Quench-ahead control 前馈控制 Put in quench gas after the bed before the T wave arrives 在温波到达床层前，打开急冷氢;Catalyst Wetting Temperature Waves 催化剂润湿温波;Controlling Exotherms with Quench-Ahead 前馈控制;Passivation of Cracking Catalysts 催化剂钝化;Passivation Is Like Titration 钝化类似滴定;Impact of Ammonia on Cracking Activity氨对裂化剂活性的影响