含氮聚合物的热氧化性能(国外英语资料).doc

含氮聚合物的热氧化性能 polyimide The thermal stability of polymers has been measured using a thermogravimetric analyzer for many years. The demand for aviation materials in todays society requires polymer composites to have high performance and high temperature resistance to meet the increasing use cycle. In the future, high polymer composites used in commercial high-speed spacecraft will have an effective life of 120000 hours at 177-232 degrees of temperature. Polyimide composites due to its excellent mechanical properties, thermal oxidation stability of high rigidity, superior quality and higher strength than the corresponding metal, which can well meet the above requirements. Used in aerospace applications, the increasing of polymer composite materials, to create a method to evaluate the material thermal and thermo oxidative stability, thus for these materials, the long-term temperature performance prediction. Based on this idea, Turk and his colleagues by thermogravimetric analysis and isothermal thermogravimetric analysis TG curves method of polyimide degradation was determined and the arrangement of the activation energy of the thermal stability and oxidation stability. The polymers involved include two types of stabilized polyimide at high temperature and two aromatic condensation polyimides, including fluorinated bonds in the two dianhydride monomers of the four polyimides. In this test, the decomposition activation energy of polyimide in atmosphere was measured by different kinetic methods. The stability of polyimide was sorted out by using this method. The traditional sequencing is based on the long-term results of isothermal ageing, weightlessness, and the thermal decomposition temperature Td in the thermogravimetric analysis data. Thermogravimetric analysis method and Fu Liye transform infrared spectroscopy combined with four kinds of polyimide can achieve degradation in air or nitrogen atmosphere when the degradation products (CO2, CO, ArNCO, and CHF3) to realize