以纸浆黑液为催化剂高变质无烟煤热天平水蒸气催化气化动力学.pdfVIP

第l3卷第6期 燃 烧 科 学 与 技 术 V01．13 No．6 200r7年12月 Journalof C啊 舶 Sdenee and Technology Dec．20Or7 以纸浆黑液为催化剂高变质无烟煤热天平 水蒸气催化气化动力学 林荣英，张济宇，林 驹，林 诚 (福州大学化学工程技术研究所，福州350002) 摘 要：以纸浆黑液为催化剂，用等温热重法研究4种高变质无烟煤常压纯水蒸气催化气化反应动力学．采用催 化剂有效因子修正缩芯模型，测定温度为750～950 oC反应控制时无烟煤碳转化率与时间的关系，并用修正缩芯模 型和修正体积模型进行较好拟合，得出这4种无烟煤水蒸气催化气化的反应速率常数、活化能和指前因子，活化能 范围为112．838～204．566 kJ／mo1．除灰含量最高的永安加筛煤以外，其他3种煤的反应速率常数都比加碳酸钠的高． 关键词：等温热重法；纸浆黑液；水蒸气催化气化；高变质无烟煤；反应动力学 中图分类号：TQ541 文献标志码：A 文章编号：1006—874o(2oo7)o6—0491-07 Catalytic Gasification Kinetics of High Metamorphosed Anthracites、 th Steam by Thermogravity Using Black Liquor of Paper Pulp Plant as Catalyst LIN Rong—ying，ZHANG Ji—yu，tan Ju，tan Cheng (Institute of Chemical Engineering and Technology，Fuzhou University，Fuzhou 350002，China) Abstr薯-ct：Using black liquor(BL)of paper pulp plant 88 catalyst，the stemn gasification kinetics offour hish metamorphosed an— thraeites Well~investigated by isothermal thermo-gravimetric analy~s under ambient pressure．The relationships of coal conversion ( )verSUS reaction time(￡)were obtained from 750 oC to 950 oC under reaction contro1．The shrinking c0re model Was modified by catalyst effective factor．The modification shrinking c0l model and the modification volumetric model weI used to well COITe— late the relationship between and ．Therefore，the l~tction rate constants，the reaction activation energy(E )and the pre-ex— ponential factor were obtained．The E ，ranging from 112．838 kJ／mol--204．566 kJ／tool was estimated by this study