水雾协同微波脱附再生树脂吸附剂.pdfVIP

中国环境科学 2016,36(9) ：2599~2605 China Environmental Science 水雾协同微波脱附再生树脂吸附剂 * 金玉娇,卢晗锋 ,周 瑛,朱秋莲,孙晓燕,陈银飞 (浙江工业大学化学工程学院,催化反应工程研究所,浙江 杭 州 310014) 摘要： 以溶剂热法合成的聚二乙烯苯(PDVB)树脂为吸附剂,苯、甲苯、二氯甲烷为典型的非极性吸附质,对比单一微波和超声雾化水协同 微波条件下树脂的脱附再生效果,考察微波功率、水雾量、吸附质种类等对树脂脱附效果的影响.结果表明,PDVB 树脂在单一微波作用下 对非极性有机分子的脱附率约为 50%,而在超声雾化水协同作用下,PDVB 对苯、甲苯、二氯甲烷的脱附率均可达到 90% 以上.同时脱附 床层的温度始终保持在 40 ℃以下,不会造成树脂高温老化,多次吸附/脱附循环再生后,树脂结构仍能保持稳定,表明在微波条件下引入超声 雾化水可强化体系的微波吸收能力,实现树脂吸附剂的快速脱附再生. 关键词：PDVB 树脂；非极性有机物；微波脱附；雾化水；再生 中图分类号：X511 文献标识码：A 文章编号：1000-6923(2016)09-2599-07 Desorption of non-polar organics on PDVB resin under microwave radiation cooperated with atomized water. JIN * Yu-jiao, LU Han-feng , ZHOU Ying, ZHU Qiu-lian, SUN Xiao-yan, CHEN Yin-fei (Institute of Catalytic Reaction Engineering, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China). China Environmental Science, 2016,36(9)：2599~2605 Abstract ：Polydivinylbenzene (PDVB) resin synthesized by solvothermal method was used as an adsorbent, and benzene, toluene and methylene chloride were selected as typical non-polar organic pollutants. Desorption performance of non-polar organic molecules on PDVB under single microwave irradiation was compared with which introduced of ultrasonic atomized water. The influence of microwave power, atomized water amount, and types of adsorbate on resin regeneration was investigated. The desorption ratio of non-polar organics is about 50% under single microwave irradiation, while the desorption ratio would reach above 90% under microwave radiation cooperated with ultrasonic atomized water in condition of 640W microwave power and 0.105g/min atomized water