TIMS测定模拟1AF料液中铀钚同位素组分.pdfVIP

第 34 卷第 5 期 核化学与放射化学 Vo l. 34 No. 5 2012年 10 月 J ournal of N uclear and Radiochemistry Oct. 2012 文章编号:0253-9950(2012)05-0305-05 TIMS 测定模拟 lAF 料液中铀杯同位素组分 蒋军清，高月华，汪南杰，姜国杜 中核四0四有限公司第三分公司，甘肃兰州 732850 摘要:采用溶剂萃取/离子交换分离-热表面电离质谱法，对模拟 1AF 料液中铀坏同位素组分测定技术进行了 研究。通过对化学分离条件、仪器测量参数、信号强度、各种干扰等测定条件的研究和选择，实现了铀、坏同位 素组分的精密测定。在选定的条件下，坝~定了模拟 1AF 料液中的铀坏同位素，主要同位素Zl5 U 和Zl9 PU 测定 精密度(s， )均优于 0.05% 。 关键词:热表面电离质谱法;1AF 料液E 铀;坏;同位素 中图分类号:0657.63 文献标志码:A Determination of Isotopic Composition of Uranium and Plutonium in Simulated lAF Feed Solution by TIMS JIANG Jun-qing , GAO Yue-hua , WANG Nan-jie , ]lANG Guo-du The Third Filial Company of 404 Company Limited , China National Nuclear Corporation , Lanzhou 732850 , China Abstract: The precise determination of the uranium and plutonium isotopic composition in the simulated 1AF feed solution by solvent extraction/ion exchange separation-thermal ioni- zation mass spectroscopy (TIMS) was studied in this paper. The precise determination of uranium and plutonium isotopic composition was realized by optimization of chemical separa- tions , and minimization of possible interferences , and proper selection of instrument parame ters. Under the selected conditions , the uranium and plutonium isotopic composition in the 1AF feed solution were accurately determined. The relative standard deviations of the main isotopes 235 U and 239 PU are less than o. 05 %. Key words: thermal ionization mass spectroscopy (TIMS); 1AF feed solution; uranium; plutonium; isotopic composition 在动力堆乏燃料后处理工艺中，1AF 料、破中铀、 位素组分中占有重要地位。但热表面电离质谱法割