X射线荧光光谱法测定高炉返粉组分.pdfVIP

中国无机分析化学 Vo l. 4 , No.1 第 4 卷第 1 期 Chinese Journal of Inorganic Analytical Chemistry 60~62 2014 年 3 月 doi:l0.3969/j.~n.209S-103S.2014.01.016 X 射线荧光光谱法测定高炉返粉组分 王曼娟刘攻戴国宣李永武方利红 (马钢检测中心理化检验一站，安徽马鞍山 243000) 摘 要 建立了 X 射线荧光光谱法测定高炉返粉中化学成分的方法，采用高温熔融法将试样制成玻璃 状体，消除了基体干扰E 通过对熔样条件、干扰元素、仪器参数、工作曲线拟合方式等方面进行实验研究， 8 确定了最佳分析条件，实现了高炉返粉中主要成分 Si0 等 种成分的同时测定，方法具有准确度高、同 2 时测定多元素、分析速度快等特点。 p 关键词 X 射线荧光光谱法;高炉返粉 多组分的测定 :0657.34jTH744.16 文献标志码:A 文章编号:2095-1035(2014)01-0060-03 中固分类号 Determination of Components of Blast Furnace Returned Powder by X-ray Fluorescence Spectrometry WANG Manjuan , LIU Yan , DAI Guoxuan , LI Yongwu ,FANG Lihong (NO.l Station of Physical Chemical lnspection. Testing Center of Ma Steel Corporation. Maanshan. Anhui 243000.China) Abstract By X-ray fluorescence spectrometry , the chernical composition of the blast furnace returned powder were determined. The samples were made into vitreous bodies by the high temperature melting method and thus eliminate matrix interference. After sample melting condition , interference elements , instrument parameters , the way of curve fitting of working curve were experimentally investigated , the optimum analysis conditions are determined. Eight main ingredients in blast furnace returned powder including Si02 were simultaneously determined. The method established in this paper has characteristics of high accuracy , fast speed and simultaneous determination , etc. Keywo