生物酶法催化火锅废油制备生物柴油.pdfVIP

第 53 卷第 6 期 湖北农业科学 Vol. 53 No.6 2014 年 3 月 Hubei Agricultural Sciences Mar. ,2014 生物酶法催化火锅废油制备生物柴油 蒋贞贞 1 ，朱俊任 2 (1.重庆工程职业技术学院，重庆 4仪泊37;2.重庆城市管理职业学院，重庆 4仪泊47) 摘要:以重庆火锅废油为原料，甲醇为量也基受体，凯泰国定化脂肪酶为催化剂，采用固定床反应体系研究 了生物酶法催化餐饮废油制备生物柴油的工艺。结果表明，经过预处理的火锅废油，分 3 次投加甲醇、正 己炕用量 1 0%、含水率 1 0%、生物酶用量 20%、水浴温度 47.5 t:，于高径比为 12.5: 1.0、柱流选为 0.6 mVrnin 的固定床装置中反应 24h，生物柴油产率达 76.59岛。采用;或压蒸饱方法精制后生物柴油产率可达 90%以 上，说明生物酶法催化火锅废油和l 备生物柴油工业化生产具有可行性。 关键词:生物感;酶催化;生物柴油;火锅废油 中图分类号:0643;Q55 文献标识码:A 文章编号:0439-8114(2014)06-1395-03 Preparation Biodiesel from Waste Cooking Oil of Hot Pot with Bio-enzyme 1 1 JIANG Zhen-zhen ,ZHU Jun-ren (1. Chongqing Institute of Engin回n吨， Chongqing 4αlO37 ， China;2. Chongqing Ci句 Mana喜;ement College , Chongqing 4αlO47 ， China) Abstract: Using waste oil of hot pot in Chongqing 田 raw rnaterial ,rnethanol as acyl acceptor. kete irnrnobilized lipase as cata- lyst , the developrnent of biodiesel frorn waste cooking oil of hot pot was studied. 响le results showed when adding methanol 3 times , lipase dosage at 2研元， n-hexane amount at 109毛， moisture content at 10%, water bath temperature under 47.5 吧， re- acting in the column wi出 a height to diameter ratio of 12.5: 1.0 at a flow rate of 0.6 ml.lmin in the f1xed bed unit for 24 h , the rate of biodiesel production was 76.5%. The rate of biodiesel production was rnore than 90% when vacu山n distillation was used. Developing biodiesel from waste cooking oil of hot pot by bio-enzyme is feasible. Key words: bio-enzyme; enzymatic; biodiesel; waste c∞king oil from hot 归t 而且